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一种通过金/铂协同二氢活化捕获的高度受限的二氢铂配合物。

A highly constrained -dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation.

作者信息

Hidalgo Nereida, de la Cruz-Martínez Felipe, Martín M Trinidad, Nicasio M Carmen, Campos Jesús

机构信息

Instituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Consejo Superior de Investigaciones Científicas (CSIC) and Universidad de Sevilla, Avenida Américo Vespucio 49, Sevilla 41092, Spain.

Departamento de Química Inorgánica, Universidad de Sevilla, Aptdo 1203, Sevilla 41071, Spain.

出版信息

Chem Commun (Camb). 2022 Aug 11;58(65):9144-9147. doi: 10.1039/d2cc03089f.

DOI:10.1039/d2cc03089f
PMID:35894238
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9367266/
Abstract

A series of Au(I)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines that stabilize both fragments allows for the isolation of a rather unique and highly distorted -type dihydride platinum(II) structure.

摘要

一系列表现为双金属受挫路易斯对的金（I）/铂（0）组合以协同方式活化氢气。稳定两个片段的三联苯膦的空间位阻使得能够分离出一种相当独特且高度扭曲的二氢化物铂（II）结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a019/9367266/929bd1d7dbc5/d2cc03089f-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a019/9367266/e2cdf167311b/d2cc03089f-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a019/9367266/ed6b8e4b8245/d2cc03089f-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a019/9367266/27a2ef6c64c5/d2cc03089f-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a019/9367266/92ce660ce040/d2cc03089f-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a019/9367266/929bd1d7dbc5/d2cc03089f-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a019/9367266/e2cdf167311b/d2cc03089f-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a019/9367266/ed6b8e4b8245/d2cc03089f-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a019/9367266/27a2ef6c64c5/d2cc03089f-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a019/9367266/92ce660ce040/d2cc03089f-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a019/9367266/929bd1d7dbc5/d2cc03089f-s3.jpg

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2
Diverse Uses of the Reaction of Frustrated Lewis Pair (FLP) with Hydrogen.受阻路易斯酸碱对（FLP）与氢反应的多种用途
J Am Chem Soc. 2021 Dec 8;143(48):20002-20014. doi: 10.1021/jacs.1c10845. Epub 2021 Nov 17.
3
Reactivity of [Pt(P Bu)] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn-Zn Bond Cleavage, and Cooperative Reactivity.
Polarized Au(I)/Rh(I) bimetallic pairs cooperatively trigger ligand non-innocence and bond activation.
手性金(I)/铑(I)双金属对协同引发配体非等药性和键活化。
Dalton Trans. 2023 Mar 21;52(12):3835-3845. doi: 10.1039/d3dt00410d.
4
Small molecule activation with bimetallic systems: a landscape of cooperative reactivity.双金属体系中小分子的活化：协同反应的全景。
Chem Commun (Camb). 2022 Oct 6;58(80):11220-11235. doi: 10.1039/d2cc04296g.
[Pt(P Bu)]与锌（I/II）化合物的反应性：双金属加合物、锌-锌键断裂及协同反应性
Organometallics. 2021 Apr 26;40(8):1113-1119. doi: 10.1021/acs.organomet.1c00088. Epub 2021 Apr 13.
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