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超临界条件下流体在聚合物工业中的应用

Application of Fluids in Supercritical Conditions in the Polymer Industry.

作者信息

Tutek Karol, Masek Anna, Kosmalska Anna, Cichosz Stefan

机构信息

Institute of Polymer and Dye Technology, Faculty of Chemistry, Lodz University of Technology, Stefanowskiego 12/16, 90-924 Lodz, Poland.

出版信息

Polymers (Basel). 2021 Feb 27;13(5):729. doi: 10.3390/polym13050729.

Abstract

This article reviews the use of fluids under supercritical conditions in processes related to the modern and innovative polymer industry. The most important processes using supercritical fluids are: extraction, particle formation, micronization, encapsulation, impregnation, polymerization and foaming. This review article briefly describes and characterizes the individual processes, with a focus on extraction, micronization, particle formation and encapsulation. The methods mentioned focus on modifications in the scope of conducting processes in a more ecological manner and showing higher quality efficiency. Nowadays, due to the growing trend of ecological solutions in the chemical industry, we see more and more advanced technological solutions. Less toxic fluids under supercritical conditions can be used as an ecological alternative to organic solvents widely used in the polymer industry. The use of supercritical conditions to conduct these processes creates new opportunities for obtaining materials and products with specialized applications, in particular in the medical, pharmacological, cosmetic and food industries, based on substances of natural sources. The considerations contained in this article are intended to increase the awareness of the need to change the existing techniques. In particular, the importance of using supercritical fluids in more industrial methods and for the development of already known processes, as well as creating new solutions with their use, should be emphasized.

摘要

本文综述了超临界条件下流体在与现代创新聚合物工业相关的工艺中的应用。使用超临界流体的最重要工艺有:萃取、颗粒形成、微粉化、包封、浸渍、聚合和发泡。这篇综述文章简要描述并表征了各个工艺,重点是萃取、微粉化、颗粒形成和包封。所提及的方法侧重于以更生态的方式进行工艺,并展示更高的质量效率。如今,由于化学工业中生态解决方案的趋势不断增长,我们看到越来越多先进的技术解决方案。超临界条件下毒性较小的流体可作为聚合物工业中广泛使用的有机溶剂的生态替代品。利用超临界条件进行这些工艺为基于天然来源物质获得具有特殊应用的材料和产品创造了新机会,特别是在医疗、制药、化妆品和食品工业中。本文中的论述旨在提高人们对改变现有技术必要性的认识。特别是,应强调在更多工业方法中使用超临界流体以及用于已知工艺开发的重要性,以及利用它们创造新解决方案的重要性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62e9/7956827/7df658cd1d8f/polymers-13-00729-g001.jpg

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