Chien Hsiu-Wen, Tsai Ming-Yen, Kuo Chia-Jung, Lin Ching-Lo
Department of Chemical and Material Engineering, National Kaohsiung University of Science and Technology, Kaohsiung 807618, Taiwan.
Photo-Sensitive Material Advanced Research and Technology Center (Photo-SMART Center), National Kaohsiung University of Science and Technology, Kaohsiung 807618, Taiwan.
Nanomaterials (Basel). 2021 Feb 27;11(3):595. doi: 10.3390/nano11030595.
In this study, a polydopamine (PDA) and polyethyleneimine (PEI)-assisted approach was developed to generate well-distributed PDA/PEI/silver (PDA/PEI/Ag) nanocomplexes on the surfaces of commercial cellulose filter papers to achieve substantial bacterial reduction under gravity-driven filtration. PDA can bind to cellulose paper and act as a reducer to produce silver nanoparticles (AgNPs), while PEI can react with oxidative dopamine and act as a dispersant to avoid the aggregation of AgNPs. The successful immobilization of PDA/PEI/Ag nanocomplexes was confirmed by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR). () and () were used as pathogen models to test the efficacy of the PDA/PEI/Ag nanocomplex-incorporated filter papers. The PDA/PEI/Ag nanocomplex-incorporated filter papers provided a substantial bacterial removal of up to 99% by simple gravity filtration. This work may be useful to develop a feasible industrial production process for the integration of biocidal AgNPs into cellulose filter paper and is recommended as a local-condition water-treatment technology to treat microbial-contaminated drinking water.
在本研究中,开发了一种聚多巴胺(PDA)和聚乙烯亚胺(PEI)辅助的方法,以在商用纤维素滤纸表面生成分布均匀的PDA/PEI/银(PDA/PEI/Ag)纳米复合物,从而在重力驱动过滤下实现显著的细菌减少。PDA可以与纤维素纸结合并作为还原剂生成银纳米颗粒(AgNPs),而PEI可以与氧化多巴胺反应并作为分散剂以避免AgNPs的聚集。通过扫描电子显微镜(SEM)、X射线衍射(XRD)和傅里叶变换红外光谱(FTIR)证实了PDA/PEI/Ag纳米复合物的成功固定。()和()被用作病原体模型来测试掺入PDA/PEI/Ag纳米复合物的滤纸的功效。通过简单的重力过滤,掺入PDA/PEI/Ag纳米复合物的滤纸可实现高达99%的显著细菌去除率。这项工作可能有助于开发一种将杀菌AgNPs整合到纤维素滤纸中的可行工业生产工艺,并被推荐作为一种处理微生物污染饮用水的因地制宜的水处理技术。