Recent Advances in Amino-Based Molecules Assisted Control of Noble-Metal Electrocatalysts.

Morphology-control synthesis is an effective means to tailor surface structure of noble-metal nanocrystals, which offers a sensitive knob for tuning their electrocatalytic properties. The functional molecules are often indispensable in the morphology-control synthesis through preferential adsorption on specific crystal facets, or controlling certain crystal growth directions. In this review, the recent progress in morphology-control synthesis of noble-metal nanocrystals assisted by amino-based functional molecules for electrocatalytic applications are focused on. Although a mass of noble-metal nanocrystals with different morphologies have been reported, few review studies have been published related to amino-based molecules assisted control strategy. A full understanding for the key roles of amino-based molecules in the morphology-control synthesis is still necessary. As a result, the explicit roles and mechanisms of various types of amino-based molecules, including amino-based small molecules and amino-based polymers, in morphology-control of noble-metal nanocrystals are summarized and discussed in detail. Also presented in this progress are unique electrocatalytic properties of various shaped noble-metal nanocrystals. Particularly, the optimization of electrocatalytic selectivity induced by specific amino-based functional molecules (e.g., polyallylamine and polyethyleneimine) is highlighted. At the end, some critical prospects, and challenges in terms of amino-based molecules-controlled synthesis and electrocatalytic applications are proposed.