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宏观石墨烯纳米片条的温度依赖性电阻率

Temperature-dependent electrical resistivity of macroscopic graphene nanoplatelet strips.

作者信息

Sibilia S, Bertocchi F, Chiodini S, Cristiano F, Ferrigno L, Giovinco G, Maffucci A

机构信息

Department of Electrical and Information Engineering, University of Cassino and Southern Lazio, Via G. di Biasio 43, 03043, Cassino, FR, Italy.

NANESA Srl, Via Del Gavardello 59/c 52100, Arezzo, AR, Italy.

出版信息

Nanotechnology. 2021 Apr 12;32(27). doi: 10.1088/1361-6528/abef95.

Abstract

This paper studies the temperature dependence of the electrical resistivity of low-cost commercial graphene-based strips, made from a mixture of epoxy and graphene nanoplatelets. An equivalent homogenous resistivity model is derived from the joint use of experimental data and simulation results obtained by means of a full three-dimensional (3D) numerical electrothermal model. Three different types of macroscopic strips (with surface dimensions of cm) are analyzed, differing in their percentage of graphene nanoplatelets. The experimental results show a linear trend of resistivity in a wide temperature range (-60°C to +60°C), and a negative temperature coefficient . The derived analytical model of temperature-dependent resistivity follows the simple law commonly adopted for conventional conducting materials, such us copper. The model is then validated by using the graphene strips as heating elements by exploiting the Joule effect. These results suggest that such materials can be used as thermistors in sensing or heating applications.

摘要

本文研究了由环氧树脂和石墨烯纳米片混合物制成的低成本商用石墨烯基条带的电阻率与温度的关系。通过联合使用实验数据和借助全三维(3D)数值电热模型获得的模拟结果,推导出了等效均匀电阻率模型。分析了三种不同类型的宏观条带(表面尺寸为厘米),它们的石墨烯纳米片百分比不同。实验结果表明,在很宽的温度范围(-60°C至+60°C)内,电阻率呈线性趋势,且具有负温度系数。所推导的与温度相关的电阻率分析模型遵循传统导电材料(如铜)通常采用的简单规律。然后,通过利用焦耳效应将石墨烯条带用作加热元件来验证该模型。这些结果表明,此类材料可在传感或加热应用中用作热敏电阻。

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