Department of Chemistry, University of Connecticut, 55 North Eagleville Road, Storrs, Connecticut 06269, USA.
Org Biomol Chem. 2021 Apr 7;19(13):2986-2990. doi: 10.1039/d1ob00251a. Epub 2021 Mar 18.
A simple, metal-free route for the oxidative esterification of aldehydes to yield hexafluoroisopropyl esters is reported. The methodology employs sodium persulfate and a catalytic quantity of a nitroxide and is applicable to aromatic, heteroaromatic, and aliphatic aldehydes.
本文报道了一种简单的、无金属的醛氧化酯化方法，可得到六氟异丙酯。该方法使用过硫酸钠和催化量的氮氧自由基，并适用于芳香醛、杂环醛和脂肪醛。
