Aksakal Resat, Mertens Chiel, Soete Matthieu, Badi Nezha, Du Prez Filip
Polymer Chemistry Research Group Centre of Macromolecular Chemistry (CMaC) Department of Organic and Macromolecular Chemistry Ghent University Krijgslaan 281 S4-bis Ghent B-9000 Belgium.
Adv Sci (Weinh). 2021 Jan 25;8(6):2004038. doi: 10.1002/advs.202004038. eCollection 2021 Mar.
In the last decade, the field of sequence-defined polymers and related ultraprecise, monodisperse synthetic macromolecules has grown exponentially. In the early stage, mainly articles or reviews dedicated to the development of synthetic routes toward their preparation have been published. Nowadays, those synthetic methodologies, combined with the elucidation of the structure-property relationships, allow envisioning many promising applications. Consequently, in the past 3 years, application-oriented papers based on discrete synthetic macromolecules emerged. Hence, material science applications such as macromolecular data storage and encryption, self-assembly of discrete structures and foldamers have been the object of many fascinating studies. Moreover, in the area of life sciences, such structures have also been the focus of numerous research studies. Here, it is aimed to highlight these recent applications and to give the reader a critical overview of the future trends in this area of research.
在过去十年中,序列定义聚合物及相关超精确、单分散合成大分子领域呈指数级增长。早期,主要发表的是致力于开发其制备合成路线的文章或综述。如今,这些合成方法与结构-性能关系的阐明相结合,使人们能够设想许多有前景的应用。因此,在过去三年中,基于离散合成大分子的面向应用的论文不断涌现。因此,诸如大分子数据存储与加密、离散结构和折叠体的自组装等材料科学应用成为了许多引人入胜的研究对象。此外,在生命科学领域,此类结构也一直是众多研究的焦点。本文旨在突出这些近期应用,并为读者提供该研究领域未来趋势的批判性概述。