Salassa Giovanni, Salassa Luca
University Hospitals of Geneva (HUG), Rue Gabrielle Perret-Gentil 4, Geneva, CH 1205, Switzerland.
Donostia International Physics Center, Paseo Manuel de Lardizabal 4, Donostia, 20018, Spain.
ACS Omega. 2021 Mar 11;6(11):7240-7247. doi: 10.1021/acsomega.0c05873. eCollection 2021 Mar 23.
This contribution highlights a number of approaches developed by coordination and organometallic chemists that go beyond mainstream inorganic reactivity. A few of these strategies have been known for decades and are fundamental tools in synthesis and catalysis, while others are more recent and still belong to a niche. Through selected examples, we show herein how transmetalation, metal exchange, metal cooperativity, and catalytic transformation of metal complexes provide unique new opportunities to expand the reactivity arsenal of inorganic systems for synthetic and technological applications.
本文着重介绍了配位化学家和有机金属化学家开发的一些超越主流无机反应性的方法。其中一些策略已经为人所知数十年，是合成和催化中的基本工具，而其他一些则是较新的，仍属于小众领域。通过选定的示例，我们在此展示了金属配合物的转金属化、金属交换、金属协同作用和催化转化如何为扩展无机体系在合成和技术应用中的反应性库提供独特的新机会。
