Heng Jerry Zhi Xiong, Tang Karen Yuanting, Regulacio Michelle D, Lin Ming, Loh Xian Jun, Li Zibiao, Ye Enyi
Institute of Materials Research and Engineering, Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Singapore 138634, Singapore.
Institute of Chemistry, University of the Philippines Diliman, Quezon City 1101, Philippines.
Nanomaterials (Basel). 2021 Mar 27;11(4):856. doi: 10.3390/nano11040856.
Titanium dioxide (TiO) nanomaterials have been ubiquitously investigated as a photocatalyst for organic contaminant treatment in wastewater due to their exemplary semiconductor properties. However, their huge band gap remains a barrier for visible light absorption, limiting their utility in practical applications. The incorporation of noble metals in the TiO scaffold would help mitigate the problem via plasmonic resonance enhancements. Silver (Ag) is the chosen noble metal as it is relatively cheap and has great plasmonic effects. In this study, the use of electrospun Ag-embedded TiO nanofibers as a photocatalyst is shown to be effective in decomposing rhodamine B and methyl orange dyes under a solar simulator in 3 h, which is more efficacious as opposed to pristine TiO nanofibers. This showcases the potential of a simple and economic wastewater treatment system for the removal of organic pollutants.
二氧化钛(TiO)纳米材料因其优异的半导体性能,作为光催化剂用于处理废水中的有机污染物已得到广泛研究。然而,其较大的带隙仍然是限制可见光吸收的障碍,限制了它们在实际应用中的效用。在TiO支架中掺入贵金属将有助于通过等离子体共振增强来缓解该问题。银(Ag)是被选用的贵金属,因为它相对便宜且具有很强的等离子体效应。在本研究中,电纺Ag嵌入TiO纳米纤维作为光催化剂在太阳模拟器下3小时内有效分解罗丹明B和甲基橙染料,这比原始TiO纳米纤维更有效。这展示了一种简单且经济的废水处理系统用于去除有机污染物的潜力。