Subsurface-Regulated PtGa Nanoparticles Confined in Silicalite-1 for Propane Dehydrogenation.

Propane dehydrogenation (PDH) is one of the most promising techniques to produce propylene. Industrial Pt-based catalysts often suffer from short-time stability under high temperature due to serious sintering and coke deposition via undesired side reactions. Detailed reaction mechanism on the surface of Pt-based nanoparticle has been well studied, while the subsurface effect remains mostly unstudied. Herein, supported PtGa nanoparticles with different surface and subsurface composition was evidenced by extended X-ray absorption fine structure (EAXFS) spectra and energy dispersive X-ray spectroscopy (EDS). Theoretical simulation demonstrated subsurface regulation would increase the electron density of surface Pt and thus weaken propylene adsorption. Propylene selectivity on the PtGa-subsurface nanoparticles was up to 98% at 600 °C while that on the Pt-subsurface nanoparticles was only 95%. Furthermore, rational designed PtGa alloy nanoparticles were encapsulated in MFI zeolite to inhibit sintering and coke deposition for enhanced catalytic stability.