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载 2-甲基-4-氯苯氧乙酸(MCPA)的海藻酸钠-壳聚糖漂浮颗粒的制备及其对水葫芦的生物活性。

Preparation of alginate-chitosan floating granules loaded with 2-methyl-4-chlorophenoxy acetic acid (MCPA) and their bioactivity on water hyacinth.

机构信息

Key Laboratory of Natural Pesticide and Chemical Biology of the Ministry of Education, South China Agricultural University, Guangzhou, China.

Guangdong Biological Pesticide Engineering Technology Research Center, South China Agricultural University, Guangzhou, China.

出版信息

Pest Manag Sci. 2021 Sep;77(9):3942-3951. doi: 10.1002/ps.6414. Epub 2021 Apr 24.

DOI:10.1002/ps.6414
PMID:33852765
Abstract

BACKGROUND

Water hyacinth (Eichhornia crassipes) is considered the most damaging aquatic weed in many countries. Chemical methods are still the primary approach to control, although this directly exposes the natural enemy of water hyacinth (water hyacinth weevil) to herbicides. In addition, spray drift can easily damage non-target plants. In this study, herbicides, natural polymer materials (chitosan and carboxymethyl chitosan), sodium alginate and natural oils (citronella oil) were used to prepare novel floating polysaccharide granules as a solution for controlling water hyacinth.

RESULTS

2-Methyl-4-chlorophenoxy acetic acid (MCPA) floating granules with a spherical structure were prepared using a MCPA-chitosan-sodium alginate-oil cross-linking and embedding method. The granules produced showed the required properties of floatation and slow controlled herbicide release. In addition, the polysaccharide granules collected around water hyacinth plants and enabled targeted release of the active herbicide ingredients onto the stems and roots of the weed, thereby stopping the herbicide from reaching non-target plants and preventing regrowth of water hyacinth.

CONCLUSION

We successfully prepared highly effective MCPA-loaded floating granules, which compared with an MCPA solution, exerted greater control on water hyacinth. Concomitantly, these granules provide a solution to spray drift and ensure the safety of natural enemies of water hyacinth, which is of great significance in research on herbicide formulations.

摘要

背景

水葫芦(凤眼蓝)被认为是许多国家最具破坏性的水生杂草。尽管化学方法仍然是控制水葫芦的主要方法,但这会使水葫芦的天敌(水葫芦象甲)直接暴露在除草剂下。此外,喷雾漂移很容易对非目标植物造成损害。在这项研究中,使用除草剂、天然聚合物材料(壳聚糖和羧甲基壳聚糖)、海藻酸钠和天然油(香茅油)来制备新型漂浮多糖颗粒,作为控制水葫芦的解决方案。

结果

采用 MCPA-壳聚糖-海藻酸钠-油交联嵌入法制备出具有球形结构的 2-甲基-4-氯苯氧乙酸(MCPA)漂浮颗粒。所制备的颗粒表现出所需的漂浮和缓慢控制除草剂释放性能。此外,多糖颗粒收集在水葫芦植物周围,能够将活性除草剂成分靶向释放到杂草的茎和根部,从而阻止除草剂到达非目标植物,并防止水葫芦再次生长。

结论

我们成功制备了高效的负载 MCPA 的漂浮颗粒,与 MCPA 溶液相比,对水葫芦的控制效果更好。同时,这些颗粒解决了喷雾漂移问题,并确保了水葫芦天敌的安全,这在除草剂制剂研究中具有重要意义。

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