Dai Chao, Chen Xiangrong, Wang Qilong, Awais Muhammad, Zhu Guangyu, Shi Yiwen, Paramane Ashish, Tanaka Yasuhiro
Zhejiang Provincial Key Laboratory of Electrical Machine Systems, College of Electrical Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China.
Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou, Zhejiang 311200, People's Republic of China.
Nanotechnology. 2021 May 14;32(31). doi: 10.1088/1361-6528/abf7ec.
This paper investigates the electrical and thermal properties of pure epoxy resin (EP) and its micro-nano hybrid composites (20 wt% micro-AlN fillers with 1 wt% and 3 wt% nano-AlOfillers; 50% micro-AlN with 3% nano-AlOfillers) for power electronic packaging applications. Electrical properties such as space charge distribution, electrical conductivity and surface potential decay are measured. The thermal performance of the fabricated samples is estimated using thermal analysis devices. The hybrid composite consisting of 20 wt% micro-AlN and 1 wt% nano-AlOfillers exhibits the least space charge accumulation, higher thermal conductivity and better thermal stability. However, the excessive addition adversely affects space charge and electrical conductivity properties. The micro-nano hybrid composites significantly exhibit higher electrical conductivity than pure EP. The microfiller addition from 20 wt% to 50 wt% significantly improves the thermal conductivity of the EP. The reduced space charge injection and accumulation in the hybrid micro-nano composites are attributed to the enhancement of the injection barrier and reduction of the charge carrier traps in these materials. A theoretical mechanism of the charge dynamics inside the samples under different test conditions is proposed to support the experimental results.
本文研究了纯环氧树脂(EP)及其微纳混杂复合材料(含20 wt%微AlN填料与1 wt%和3 wt%纳米AlO填料;50%微AlN与3%纳米AlO填料)用于电力电子封装应用时的电学和热学性能。测量了空间电荷分布、电导率和表面电位衰减等电学性能。使用热分析设备评估了所制备样品的热性能。由20 wt%微AlN和1 wt%纳米AlO填料组成的混杂复合材料表现出最少的空间电荷积累、更高的热导率和更好的热稳定性。然而,过量添加会对空间电荷和电导率性能产生不利影响。微纳混杂复合材料的电导率明显高于纯EP。微填料从20 wt%添加到50 wt%显著提高了EP的热导率。混杂微纳复合材料中空间电荷注入和积累的减少归因于这些材料中注入势垒的增强和电荷载流子陷阱的减少。提出了不同测试条件下样品内部电荷动力学的理论机制以支持实验结果。