Wu Pingfan, Wang Yu, Huang Bo, Xiao Zicheng
Institute of POM-based Materials, Hubei Provincial Key Laboratory of Green Materials for Light Industry, School of Materials and Chemical Engineering, Hubei University of Technology, Wuhan 430068, China.
Nanoscale. 2021 Apr 21;13(15):7119-7133. doi: 10.1039/d1nr00397f. Epub 2021 Apr 13.
Anderson-type polyoxometalates (POMs) are one of the most important groups of the POM family. In the past decade, the functionalization of Anderson-type POMs has achieved significant progress and these materials have already shown unique charm in catalysis, molecular devices, energy materials, and inorganic biochemical drugs. In particular, their highly flexible topological structure and diverse functionalization methods make them the most convenient and universal platforms for rational design and controllable synthesis. This review provides a deep discussion on the recent progress in the synthetic methodology, structural exploration, and promising applications of Anderson-type POMs. It also summarizes the latest research directions and provides future prospects.
安德森型多金属氧酸盐（POMs）是多金属氧酸盐家族中最重要的类别之一。在过去十年中，安德森型多金属氧酸盐的功能化取得了显著进展，这些材料在催化、分子器件、能源材料和无机生化药物等领域已展现出独特魅力。特别是，它们高度灵活的拓扑结构和多样的功能化方法使其成为合理设计和可控合成最便捷、通用的平台。本文综述深入探讨了安德森型多金属氧酸盐在合成方法、结构探索及应用前景方面的最新进展。还总结了最新研究方向并展望了未来。
