Li Ai-Juan, Huang Sheng-Li, Yang Guo-Yu
MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, China.
Dalton Trans. 2023 Dec 12;52(48):18133-18136. doi: 10.1039/d3dt03274d.
Anderson-type polyoxometalates have exhibited remarkable catalytic capabilities in a wide range of reactions. This discourse delves into the distinct categories of Anderson POMs and their respective catalytic reactions, which are examined in separate segments. These encompass the straightforward {XMo} POMs, the organic grafting {XMo} POMs, and the integration of POMs into POM cluster organic frameworks. It is important to highlight that specific catalytic functionalities can solely be accomplished the utilization of Anderson-type POMs, thus emphasizing their indispensable role in future explorations.
安德森型多金属氧酸盐在广泛的反应中展现出了卓越的催化能力。本文深入探讨了安德森多金属氧酸盐的不同类别及其各自的催化反应，这些将在不同部分进行研究。其中包括简单的{XMo}多金属氧酸盐、有机接枝{XMo}多金属氧酸盐以及将多金属氧酸盐整合到多金属氧酸盐簇有机框架中。需要强调的是，特定的催化功能只能通过使用安德森型多金属氧酸盐来实现，从而突出了它们在未来探索中不可或缺的作用。
