并五苯-菲并苯混合分子（= 5-7）的光化学合成及器件应用。
Photochemical synthesis and device application of acene-phenacene hybrid molecules, dibenzo[]phenacenes ( = 5-7).
机构信息
Research Institute for Interdisciplinary Science, Okayama University, Okayama 700-8530, Japan.
Institute for Materials Chemistry and Engineering, Kyushu University, Fukuoka 819-0395, Japan.
出版信息
Chem Commun (Camb). 2021 May 13;57(39):4768-4771. doi: 10.1039/d1cc01294k.
PMID:33890583
Abstract
Dibenzo[n]phenecenes (DBnPs, n = 5-7) were conveniently synthesised through Mallory photocyclization as the key step. Effective mobilities of single-crystal field-effect transistors of DBnPs were evaluated to demonstrate that C2h-symmetrical DB6P shows higher performance than C2v-symmetrical DB5P and DB7P.
摘要
二苯并[n]菲（DBnPs，n=5-7）可通过 Mallory 光环化反应方便地合成，这是关键步骤。通过评估 DBnPs 单晶场效应晶体管的有效迁移率，证明 C2h 对称的 DB6P 比 C2v 对称的 DB5P 和 DB7P 具有更高的性能。
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