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最近作为化学和生物探针的金属环戊二烯基铱(III)配合物的发展和应用。

Recent development and application of cyclometalated iridium(III) complexes as chemical and biological probes.

机构信息

Graphene Composite Research Center, College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, Guangdong 518060, PR China.

出版信息

Dalton Trans. 2021 May 18;50(19):6410-6417. doi: 10.1039/d1dt00592h.

DOI:10.1039/d1dt00592h
PMID:33900334
Abstract

Iridium complexes have been widely applied as molecular sensors because of their rich photophysical properties, including large Stokes shifts, long emission lifetimes, environment-sensitive emissions, and high luminescence quantum yields. In this paper, we review the recent development and application of iridium complexes as probes for ions, anions, gaseous species, organic molecules, small biomolecules, biomacromolecules, and subcellular organelles. Our outlook for iridium-based probes is also discussed.

摘要

铱配合物由于其丰富的光物理性质,包括大斯托克斯位移、长荧光寿命、对环境敏感的发射和高光致发光量子产率,已被广泛应用于分子传感器。在本文中,我们综述了铱配合物作为离子、阴离子、气态物质、有机分子、小分子生物分子、生物大分子和亚细胞细胞器探针的最新发展和应用。我们还讨论了基于铱的探针的前景。

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