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十年来 MXenes 在水净化领域的探索:涵盖了广泛的污染物、当前的挑战和未来的趋势。

A decade of exploring MXenes as aquatic cleaners: Covering a broad range of contaminants, current challenges and future trends.

机构信息

Environmental Nanoscience Laboratory, Department of Earth Sciences, Indian Institute of Science Education and Research (IISER) Kolkata, Mohanpur, West Bengal, India, 741246.

Environmental Nanoscience Laboratory, Department of Earth Sciences, Indian Institute of Science Education and Research (IISER) Kolkata, Mohanpur, West Bengal, India, 741246; Centre for Climate and Environmental Studies, Indian Institute of Science Education and Research (IISER) Kolkata, Mohanpur, West Bengal, 741246, India.

出版信息

Chemosphere. 2021 Sep;279:130587. doi: 10.1016/j.chemosphere.2021.130587. Epub 2021 Apr 16.

DOI:10.1016/j.chemosphere.2021.130587
PMID:33901892
Abstract

Clean water, the elixir of life, is of tremendous importance in achieving environmental sustainability and the balanced functioning of our ecosystem. Coupled with population growth, several anthropogenic activities and environmental catastrophes have together contributed to an alarming increase in the concentration of toxic pollutants in water bodies. Diversified physiochemical conditions of water matrices, ranging from mining drainage to seawater, is the critical challenge in designing adsorbents. MXenes, a new class of 2D layered materials, are transition metal nitrides, carbides, carbonitrides or borides formed through selective etching process. MXenes are known to have high surface area and activity with biological compatibility and chemical stability and therefore are promising adsorbents and have been explored for a broad range of contaminants. This review starts with a brief about environmental contaminants followed by synthesis and modifications of MXenes. It then revolves around their so far explored adsorbing and degradation properties for different contaminants ranging from toxic metals, inorganic ions, and radionuclides to various organic pollutants, including dyes, pharmaceuticals, aromatic hydrocarbons, and pesticides, etc. Finally, we have discussed associated toxicity, secondary contamination, future trends, and challenges in ascertaining scalability and wide-range applicability of MXenes in natural environmental conditions to make them a warrior of water sustainability.

摘要

清洁水,生命之精华,对于实现环境可持续性和生态系统的平衡功能至关重要。加之人口增长,多种人为活动和环境灾难共同导致水体中有毒污染物浓度令人震惊地增加。水基质的多样化物理化学条件,从矿山排水到海水,是设计吸附剂的关键挑战。MXenes 是一种新型二维层状材料,是通过选择性刻蚀工艺形成的过渡金属氮化物、碳化物、碳氮化物或硼化物。MXenes 具有高表面积和活性,具有生物相容性和化学稳定性,因此是很有前途的吸附剂,并已被广泛探索用于各种污染物。这篇综述首先简要介绍了环境污染物,然后介绍了 MXenes 的合成和修饰。然后围绕它们迄今为止探索的不同污染物的吸附和降解特性展开讨论,这些污染物包括有毒金属、无机离子和放射性核素以及各种有机污染物,如染料、药物、芳烃和农药等。最后,我们讨论了相关毒性、二次污染、未来趋势以及在确定 MXenes 在自然环境条件下的可扩展性和广泛适用性方面的挑战,以使它们成为水可持续性的战士。

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