Department of Chemical Science and Technologies, University of Rome Tor Vergata, 00133 Rome, Italy.
Department of Chemistry, University of Roma La Sapienza, 00185 Rome, Italy.
Dalton Trans. 2021 May 4;50(17):5724-5731. doi: 10.1039/d1dt00528f.
The development of chemical sensors is an urgent need for both environmental and health issues. The breakthrough needed for the advancement of these devices is the development of efficient receptors. Porphyrins have been widely used as sensing layers in chemical sensors, but their integration with nanostructures can greatly boost the performance of these macrocycles, improving from one side the stability of the sensing layer, and from the other, offering additional interaction mechanisms with target analytes. We present here some recent examples of hybrid materials prepared by the integration of porphyrins with metal and metal oxide nanoparticles, porphyrin-based metal organic frameworks and their exploitation as sensing layers in chemical sensors.
化学传感器的发展对于环境和健康问题都是迫切需要的。这些器件的发展需要突破的是高效受体的开发。卟啉类化合物已被广泛用作化学传感器中的传感层,但将其与纳米结构集成可以极大地提高这些大环化合物的性能,一方面提高传感层的稳定性,另一方面提供与目标分析物的额外相互作用机制。本文介绍了一些最近的例子,即将卟啉与金属和金属氧化物纳米粒子、基于卟啉的金属有机骨架集成的杂化材料,并将其作为化学传感器中的传感层进行了应用。