Magna Gabriele, Mandoj Federica, Stefanelli Manuela, Pomarico Giuseppe, Monti Donato, Di Natale Corrado, Paolesse Roberto, Nardis Sara
Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma Tor Vergata, Via della Ricerca Scientifica, 1, 00133 Rome, Italy.
Dipartimento di Medicina Molecolare e Traslazionale, Università di Brescia, Viale Europa 11, 25123 Brescia, Italy.
Nanomaterials (Basel). 2021 Apr 13;11(4):997. doi: 10.3390/nano11040997.
Porphyrins and carbon nanomaterials are among the most widely investigated and applied compounds, both offering multiple options to modulate their optical, electronic and magnetic properties by easy and well-established synthetic manipulations. Individually, they play a leading role in the development of efficient and robust chemical sensors, where they detect a plethora of analytes of practical relevance. But even more interesting, the merging of the peculiar features of these single components into hybrid nanostructures results in novel materials with amplified sensing properties exploitable in different application fields, covering the areas of health, food, environment and so on. In this contribution, we focused on recent examples reported in literature illustrating the integration of different carbon materials (i.e., graphene, nanotubes and carbon dots) and (metallo)porphyrins in heterostructures exploited in chemical sensors operating in liquid as well as gaseous phase, with particular focus on research performed in the last four years.
卟啉和碳纳米材料是研究和应用最为广泛的化合物之一,通过简单且成熟的合成操作,二者都提供了多种调节其光学、电子和磁性特性的选择。它们各自在高效且耐用的化学传感器开发中发挥着主导作用,能够检测大量具有实际意义的分析物。但更有趣的是,将这些单一成分的独特特性融合到混合纳米结构中,会产生具有增强传感特性的新型材料,可用于不同的应用领域,涵盖健康、食品、环境等领域。在本论文中,我们重点关注了文献中报道的近期实例,这些实例展示了不同碳材料(即石墨烯、纳米管和碳点)与(金属)卟啉在液相和气相化学传感器中所采用的异质结构中的整合情况,特别关注了过去四年所开展的研究。