School of Chemistry, Cardiff University, Park Place, Main Building, Cardiff, CF10 3AT, UK.
Chem Rec. 2021 Sep;21(9):2526-2537. doi: 10.1002/tcr.202100064. Epub 2021 May 7.
Organosulfur compounds are being widely used in medicinal chemistry, as well as in organic transformations and in synthetic applications. Because of their interest in many areas, the development of sustainable and green synthetic methods to access various organosulfur compounds has a high influence on the chemistry community. Electroorganic synthesis has become a very valuable methodology for the synthesis of organosulfur compounds during the last decade. The use of electrochemical technology offers a green, sustainable and safe alternative to prepare and modify such compounds. This review summarises recent developments in the preparation of organosulfur compounds such as sulfoxides, sulfones, sulfinic esters, sulfonamides, thiosulfonates, sulfonyl fluorides and sulfoximines under electrochemical reaction conditions.
有机硫化合物在药物化学、有机转化和合成应用中得到了广泛的应用。由于它们在许多领域的重要性，开发可持续和绿色的合成方法来获得各种有机硫化合物对化学界有很大的影响。电化学合成在过去十年中已成为合成有机硫化合物的一种非常有价值的方法。电化学技术的使用为制备和修饰此类化合物提供了一种绿色、可持续和安全的替代方法。本文综述了近年来在电化学反应条件下制备亚砜、砜、亚磺酸酯、磺胺、硫代硫酸盐、砜氟和亚磺酰胺等有机硫化合物的最新进展。
