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利用超薄石墨相氮化碳纳米片的开启型荧光对乳制品中的三聚氰胺进行高灵敏和选择性检测。

Highly sensitive and selective detection of melamine in dairy products by turn-on fluorescence of ultrathin graphitic carbon nitride nanosheets.

机构信息

Key Laboratory of Functional Inorganic Material Chemistry (MOE), School of Chemistry and Material Science, Heilongjiang University, Harbin, China.

出版信息

Luminescence. 2021 Dec;36(8):1885-1890. doi: 10.1002/bio.4094. Epub 2021 Oct 14.

Abstract

There is an important and realistic need to develop a practical sensor for melamine in dairy products that is highly sensitive and selective. However, the complicated composition and environment in milk necessitate the use of a stable luminophore as the sensor, as well as excellent photophysical properties. Here, ultrathin graphitic carbon nitride nanosheet (CNNS) was prepared by successive thermal polymerization and acid exfoliation. The photophysical properties of CNNS include its strong ultraviolet absorption and intense blue-light emission. Notably, CNNS could act as a chemo-sensor to detect trace melamine in dairy products. The high stability, eminent sensitivity, powerful selectivity, and competitiveness all substantiate the findings that this CNNS luminophore is a promising sensor for melamine in dairy products, and has potential practical value for monitoring milk quality.

摘要

开发一种对乳制品中的三聚氰胺具有高灵敏度和选择性的实用传感器具有重要的现实需求。然而,牛奶中复杂的组成和环境需要使用稳定的发光体作为传感器,同时还需要具备优异的光物理性能。在这里,通过连续的热聚合和酸剥离制备了超薄石墨相氮化碳纳米片(CNNS)。CNNS 的光物理性质包括其强的紫外吸收和强烈的蓝光发射。值得注意的是,CNNS 可以作为化学传感器来检测乳制品中的痕量三聚氰胺。高稳定性、高灵敏度、强选择性和竞争力都证明了这种 CNNS 发光体是一种有前途的乳制品中三聚氰胺传感器,具有监测牛奶质量的潜在实用价值。

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