Modified Shell Carbon with Enhanced Performance for the Adsorption of Cooking Fumes.

Using shell (COS) as a raw material and phosphoric acid as the activator, activated shell carbon (COSC-0) was prepared and then modified by Fenton's reagent (named as COSC-1). SEM, GC-MS, FTIR, and specific surface area and pore analyzers were used to study the adsorption performance of COS, COSC-0, and COSC-1 on cooking fumes. Results showed that COSC-1 was the best adsorbent compared with COS and COSC-0. The adsorption quantity and penetrating time of COSC-1 were 44.04 mg/g and 4.1 h, respectively. Most aldehydes could be adsorbed by COSC-1, which was due to the large number of carbonyl and carboxyl groups generated on the surface of COSC-1 from the action of Fenton's reagent. The adsorption effect of COSC-1 on different types of pollutants in cooking fumes was analyzed based on the similar compatibility principle. COSC-1 showed a much higher adsorption effect on the strong polarity functional groups than on weak polar groups. The results provide a theoretical basis for the application of shell carbon adsorption technology in the treatment of cooking fumes.