Suppr超能文献

基于聚苯乙烯的复合材料中紫外还原氧化石墨烯薄片的磁化

Magnetization of Ultraviolet-Reduced Graphene Oxide Flakes in Composites Based on Polystyrene.

作者信息

Ionov Alexander N, Volkov Mikhail P, Nikolaeva Marianna N, Smyslov Ruslan Y, Bugrov Alexander N

机构信息

Ioffe Institute, Politekhnicheskaya 26, 194021 St. Petersburg, Russia.

Institute of Macromolecular Compounds, Russian Academy of Sciences, Bolshoy pr-t 31, 199004 St. Petersburg, Russia.

出版信息

Materials (Basel). 2021 May 12;14(10):2519. doi: 10.3390/ma14102519.

Abstract

This work presents our study results of the magnetization of multilayer UV-reduced graphene oxide (UV-rGO), polymer matrix (polystyrene), and a conjugated composite based on them. The mesoscopic structure of the composites synthesized in this work was studied by such methods as X-ray diffraction, SEM, as well as NMR-, IR- and Raman spectroscopy. The magnetization of the composites under investigation and their components was measured using a vibrating-sample magnetometer. It has been shown that the UV-reduction process leads to the formation of many submicron holes distributed inside rGO flakes, which can create edge defects, causing possibly magnetic order in the graphite samples under investigation on the mesoscopic level. This article provides an alternative explanation for the ferromagnetic hysteresis loop in UV-rGO on the base of superconductivity type-II.

摘要

这项工作展示了我们对多层紫外线还原氧化石墨烯(UV-rGO)、聚合物基体(聚苯乙烯)以及基于它们的共轭复合材料的磁化研究结果。通过X射线衍射、扫描电子显微镜(SEM)以及核磁共振(NMR)、红外(IR)和拉曼光谱等方法研究了本工作中合成的复合材料的介观结构。使用振动样品磁强计测量了所研究的复合材料及其组分的磁化强度。结果表明,紫外线还原过程导致在rGO薄片内部形成许多亚微米级的孔洞,这会产生边缘缺陷,可能在介观层面上使所研究的石墨样品产生磁有序。本文基于II型超导性为UV-rGO中的铁磁滞回线提供了另一种解释。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf5e/8151044/27d207355c40/materials-14-02519-g001.jpg

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验