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从. 中分离得到三种新的倍半萜多元醇酯。

Three new sesquiterpene polyol esters from .

机构信息

High & New Technology Research Center of Henan Academy of Science, Zhengzhou 450002 PR China.

Key Laboratory of Natural Products of Henan Academy of Science, Zhengzhou 450002, PR China.

出版信息

J Asian Nat Prod Res. 2022 Apr;24(4):336-343. doi: 10.1080/10286020.2021.1931140. Epub 2021 Jun 7.

Abstract

Three new sesquiterpene polyol ester compounds angulatins S-U, together with three known compounds were isolated from Maxim. According to mainly 1D NMR and 2D NMR analysis, the structures of the new compounds were completely determined as angulatin S (1β-furoyloxy-2β,8α-diisobutanoyloxy-9β-benzoyloxy-15-acetoxy-4α,6α-dihydroxy-β-dihydroagarofuran), angulatin T (1β,2β,6α-triacetoxy-8β,15-diisobutanoyloxy-9α-benzoyloxy-β-dihydroagrofuran), and angulatin U (1β,6α,15-triacetoxy-8β-isobutanoyloxy-9α-benzoyloxy-β-dihydroagarofuran).

摘要

从八角茴香中分离得到三个新的倍半萜多元醇酯化合物 angulatins S-U,以及三个已知化合物。根据主要的 1D NMR 和 2D NMR 分析,完全确定了新化合物的结构,分别为 angulatin S(1β-呋喃酰氧基-2β,8α-二异丁酰氧基-9β-苯甲酰氧基-15-乙酰氧基-4α,6α-二羟基-β-二氢agarofuran)、angulatin T(1β,2β,6α-三乙酰氧基-8β,15-二异丁酰氧基-9α-苯甲酰氧基-β-二氢agarofuran)和 angulatin U(1β,6α,15-三乙酰氧基-8β-异丁酰氧基-9α-苯甲酰氧基-β-二氢agarofuran)。

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