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碳纤维增强高负载纳米铝热剂的传播:微观燃烧的原位观察

Carbon Fibers Enhance the Propagation of High Loading Nanothermites: In Situ Observation of Microscopic Combustion.

作者信息

Wang Haiyang, Kline Dylan J, Rehwoldt Miles C, Zachariah Michael R

机构信息

Department of Chemical and Environmental Engineering, The University of California Riverside, Riverside, California 92521, United States.

Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, Maryland 20742, United States.

出版信息

ACS Appl Mater Interfaces. 2021 Jul 7;13(26):30504-30511. doi: 10.1021/acsami.1c02911. Epub 2021 Jun 25.

Abstract

A major challenge in formulating and manufacturing energetic materials lies in the balance between total energy density, energy release rate, and mechanical integrity. In this work, carbon fibers are embedded into ∼90 wt % loading Al/CuO nanothermite sticks through a simple extrusion direct writing technique. With only ∼2.5 wt % carbon fiber addition, the burn rate and heat flux were promoted >2×. In situ microscopic observation of combustion shows that the carbon fiber intercept ejected hot agglomerates near the burning surface and enhanced heat feedback to the unreacted material. This study outlines how these approaches may enhance the propagation and reduce the two-phase flow losses.

摘要

在含能材料的配方设计和制造中,一个主要挑战在于总能量密度、能量释放速率和机械完整性之间的平衡。在这项工作中,通过一种简单的挤出直写技术,将碳纤维嵌入到负载量约为90 wt%的铝/氧化铜纳米铝热剂棒中。仅添加约2.5 wt%的碳纤维,燃烧速率和热通量就提高了2倍以上。燃烧的原位微观观察表明,碳纤维截获了在燃烧表面附近喷出的热团聚物,并增强了对未反应材料的热反馈。这项研究概述了这些方法如何促进传播并减少两相流损失。

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