Gurtner Christian, Wun Aetna W, Sailor Michael J
Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093-0358 (USA), Fax: (+1) 619-534-5383.
Angew Chem Int Ed Engl. 1999 Jul 12;38(13-14):1966-1968. doi: 10.1002/(SICI)1521-3773(19990712)38:13/14<1966::AID-ANIE1966>3.0.CO;2-5.
Functionalization of hydride-terminated porous and single-crystal silicon surfaces with organic species is accomplished by electrochemical reduction of organo iodides and organo bromides (see scheme). This new method is fast and efficient, and achieves high surface coverage with functionalized and nonfunctionalized alkyl and benzyl groups within minutes.
通过有机碘化物和有机溴化物的电化学还原，可实现氢化物封端的多孔和单晶硅表面与有机物种的功能化（见图）。这种新方法快速高效，能在几分钟内实现功能化和未功能化的烷基及苄基的高表面覆盖率。
