全氟烷基乙烯的马尔科夫尼科夫硼氢化反应。
Markovnikov Hydroboration of Perfluoroalkylethylenes.
作者信息
Brown Herbert C, Chen Guang-Ming, Jennings Michael P, Ramachandran P Veeraraghavan
机构信息
H. C. Brown and R. B. Wetherill Laboratories of Chemistry, Purdue University, West Lafayette, IN 47907-1393 (USA), Fax: (+1) 765-494-0239.
出版信息
Angew Chem Int Ed Engl. 1999 Jul 12;38(13-14):2052-2054. doi: 10.1002/(SICI)1521-3773(19990712)38:13/14<2052::AID-ANIE2052>3.0.CO;2-9.
Abstract
A Markovnikov regioselectivity of 92 % or higher is achieved in the hydroboration of a series of perfluoroalkylethylenes and 2',3',4',5',6'-pentafluorostyrene with dichloro- and dibromoborane to provide the corresponding (fluoroalkyl)dihaloboranes (see reaction).
摘要
一系列全氟烷基乙烯和2',3',4',5',6'-五氟苯乙烯与二氯硼烷和二溴硼烷进行硼氢化反应时，可实现92%或更高的马氏区域选择性，从而得到相应的（氟烷基）二卤硼烷（见反应）。
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