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磷石膏及其在克罗地亚的潜在用途:挑战与机遇。

Phosphogypsum and its potential use in Croatia: challenges and opportunities.

机构信息

Institute for Medical Research and Occupational Health, Zagreb, Croatia.

出版信息

Arh Hig Rada Toksikol. 2021 Jun 28;72(3):93-100. doi: 10.2478/aiht-2021-72-3504.

DOI:10.2478/aiht-2021-72-3504
PMID:34187110
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8265199/
Abstract

Phosphogypsum (PG) is a waste by-product (residue) originating from the production of phosphoric acid and phosphate fertilisers. PG contains chemical and radioactive impurities, which is why it is mostly stockpiled in controlled areas. Worldwide, only about 15 % of PG is recycled or reused. Today, policies and business strategies prioritise sustainable development through circular economy, which certainly includes PG. This provides new opportunities for Croatia to manage its PG and make an effort to use it as an additive in different industries, such as agriculture and construction. Due to its chemical and radiological properties, PG can potentially cause problems for the environment and human health. Hence, before using PG, detailed knowledge of potential hazards is necessary to protect people and the environment. The aim of this review is to summarise available data on Croatian PG, compare them with other countries, and to identify knowledge gaps and the lack of data on potential hazardous substances in PG in order to assess the opportunities of using PG in Croatia.

摘要

磷石膏(PG)是生产磷酸和磷肥的副产品(残余物)。PG 含有化学和放射性杂质,这就是为什么它主要储存在控制区域。在全球范围内,只有约 15%的 PG 被回收或再利用。如今,政策和商业战略通过循环经济优先考虑可持续发展,这当然包括 PG。这为克罗地亚管理其 PG 并努力将其用作农业和建筑等不同行业的添加剂提供了新的机会。由于其化学和放射性特性,PG 可能对环境和人类健康造成问题。因此,在使用 PG 之前,需要详细了解潜在危害的知识,以保护人和环境。本综述的目的是总结有关克罗地亚 PG 的现有数据,将其与其他国家进行比较,并确定 PG 中潜在危险物质的数据缺口和缺乏,以评估在克罗地亚使用 PG 的机会。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d785/8265199/0bf3c0752e29/aiht-72-093-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d785/8265199/0bf3c0752e29/aiht-72-093-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d785/8265199/0bf3c0752e29/aiht-72-093-g001.jpg

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本文引用的文献

1
Distribution of uranium and thorium chains radionuclides in different fractions of phosphogypsum grains.铀和钍链放射性核素在磷石膏颗粒不同粒级中的分布。
Environ Sci Pollut Res Int. 2020 May;27(13):15856-15868. doi: 10.1007/s11356-020-08090-y. Epub 2020 Feb 24.
2
Effect of phosphogypsum on growth, physiology, and the antioxidative defense system in sunflower seedlings.磷石膏对向日葵幼苗生长、生理和抗氧化防御系统的影响。
Environ Sci Pollut Res Int. 2015 Oct;22(19):14829-40. doi: 10.1007/s11356-015-4716-z. Epub 2015 May 21.
3
Measuring and modelling the radiological impact of a phosphogypsum deposition site on the surrounding environment.
测量和模拟磷石膏堆放场对周围环境的辐射影响。
Arh Hig Rada Toksikol. 2015 Mar;66(1):31-40. doi: 10.1515/aiht-2015-66-2587.
4
Implications for food safety of the uptake by tomato of 25 trace-elements from a phosphogypsum amended soil from SW Spain.从西班牙西南部的一个磷石膏改良土壤中摄取 25 种微量元素对番茄食品安全的影响。
J Hazard Mater. 2014 Feb 15;266:122-31. doi: 10.1016/j.jhazmat.2013.12.019. Epub 2013 Dec 21.
5
A new approach to determine the phosphogypsum spread from the deposition site into the environment.一种新方法可用于确定磷石膏从沉积地点向环境中的扩散情况。
J Hazard Mater. 2013 Oct 15;261:584-92. doi: 10.1016/j.jhazmat.2013.08.012. Epub 2013 Aug 12.
6
Analysis of naturally-occurring radionuclides in coal combustion fly ash, gypsum, and scrubber residue samples.分析燃煤飞灰、石膏和洗涤器残渣样品中的天然放射性核素。
Health Phys. 2013 Mar;104(3):264-9. doi: 10.1097/HP.0b013e318279f3bf.
7
Natural radioactivity in building materials in the European Union: a database and an estimate of radiological significance.建筑材料中的天然放射性:数据库和辐射意义评估。
J Environ Radioact. 2012 Feb;105:11-20. doi: 10.1016/j.jenvrad.2011.10.001. Epub 2011 Nov 10.
8
Environmental impact and management of phosphogypsum.磷石膏的环境影响与管理
J Environ Manage. 2009 Jun;90(8):2377-86. doi: 10.1016/j.jenvman.2009.03.007. Epub 2009 Apr 29.
9
Behaviour and fluxes of natural radionuclides in the production process of a phosphoric acid plant.磷酸厂生产过程中天然放射性核素的行为与通量
Appl Radiat Isot. 2009 Feb;67(2):345-56. doi: 10.1016/j.apradiso.2008.10.012. Epub 2008 Oct 29.
10
Radioactive contamination in Croatia by phosphate fertilizer production.克罗地亚磷肥生产造成的放射性污染。
J Hazard Mater. 2009 Mar 15;162(2-3):1199-203. doi: 10.1016/j.jhazmat.2008.06.005. Epub 2008 Jun 8.