Prosthodontic Department, College of Dentistry, University of Babylon, Iraq.
Oral and Maxillofacial Surgery Department, College of Dentistry, University of Babylon, Iraq.
Biomed Res Int. 2021 Jun 10;2021:9934073. doi: 10.1155/2021/9934073. eCollection 2021.
This paper reports the corrosion behavior of uncoated commercially pure titanium and Ti-6Al-4V samples and these coated with hydroxyapatite, partial stabilized zirconia (PSZ), and the mixture of partial stabilized zirconia and hydroxyl-apatite by measuring passivation current density and see if there are any differences between them using electrochemical polarization tests in 37°C Hank's solution.
The electrophoretic deposition method (EPD) was elected to keep the coating materials which are HA, PSZ, and the mixture of 50% HA and 50% PSZ on Cp Ti and Ti-6Al-4V alloy samples. The electrochemical corrosion test was achieved by exposing the coated and uncoated samples to Hank's solution which prepared in the laboratory and measuring the polarization potential, passivation current density, and the open circuit potential for all samples.
The results indicated that the passivation current density for all Cp Ti and Ti-6Al-4V alloy groups that coated with HA, PSZ, and with mixture of 50/50 HA and PSZ was less than uncoated groups. There are no significant differences between all Cp Ti groups when compared with all Ti-6Al-4 V alloy groups. The open circuit potential (OCP) for both Cp Ti and Ti -6Al -4V samples was in the following sequence PSZ > HA > mixture of HA and PSZ > uncoated.
Coating significantly decreased the passivation current density of Cp Ti and Ti-6Al-4V alloy.
本论文报告了未涂层商业纯钛和 Ti-6Al-4V 样品以及涂覆有羟基磷灰石、部分稳定氧化锆(PSZ)和部分稳定氧化锆与羟基磷灰石混合物的涂层的腐蚀行为,通过在 37°C 的 Hank's 溶液中使用电化学极化测试来测量钝化电流密度,并观察它们之间是否存在差异。
采用电泳沉积法(EPD)将涂层材料(HA、PSZ 和 50%HA 和 50%PSZ 的混合物)保持在 Cp Ti 和 Ti-6Al-4V 合金样品上。通过将涂覆和未涂覆的样品暴露于实验室制备的 Hank's 溶液中,并测量所有样品的极化电位、钝化电流密度和开路电位来进行电化学腐蚀测试。
结果表明,所有涂覆有 HA、PSZ 和 50/50HA 和 PSZ 混合物的 Cp Ti 和 Ti-6Al-4V 合金组的钝化电流密度均低于未涂覆组。与所有 Ti-6Al-4V 合金组相比,所有 Cp Ti 组之间没有显著差异。Cp Ti 和 Ti-6Al-4V 样品的开路电位(OCP)按以下顺序排列:PSZ > HA > HA 和 PSZ 的混合物>未涂覆。
涂层显著降低了 Cp Ti 和 Ti-6Al-4V 合金的钝化电流密度。