• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

为何导电性并非总是关键——决定基于二维金属有机框架的双电层电容器超级电容器电极电容的物理性质:以Ni(HITP)为例的研究

Why conductivity is not always king - physical properties governing the capacitance of 2D metal-organic framework-based EDLC supercapacitor electrodes: a Ni(HITP) case study.

作者信息

Borysiewicz Michał Adam, Dou Jin-Hu, Stassen Ivo, Dincă Mircea

机构信息

Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

出版信息

Faraday Discuss. 2021 Oct 15;231(0):298-304. doi: 10.1039/d1fd00028d.

DOI:10.1039/d1fd00028d
PMID:34259286
Abstract

We report a systematic study on the variation of the physical properties of Ni(HITP) (HITP = 2,3,6,7,10,11-hexaiminotriphenylene) in the context of their influence on the capacitive behavior of this material in supercapacitor electrodes prepared using the neat MOF. We find that, for this representative material, the sample morphology has a greater impact on the measured electrode performance than differences in bulk electrical conductivity.

摘要

我们报告了一项关于Ni(HITP)(HITP = 2,3,6,7,10,11 - 六亚氨基三亚苯)物理性质变化的系统研究,该研究考察了这些性质对使用纯金属有机框架(MOF)制备的超级电容器电极中这种材料电容行为的影响。我们发现,对于这种具有代表性的材料,样品形态对测量的电极性能的影响比体电导率差异更大。

相似文献

1
Why conductivity is not always king - physical properties governing the capacitance of 2D metal-organic framework-based EDLC supercapacitor electrodes: a Ni(HITP) case study.为何导电性并非总是关键——决定基于二维金属有机框架的双电层电容器超级电容器电极电容的物理性质:以Ni(HITP)为例的研究
Faraday Discuss. 2021 Oct 15;231(0):298-304. doi: 10.1039/d1fd00028d.
2
Coupling of a conductive Ni(2,3,6,7,10,11-hexaiminotriphenylene) metal-organic framework with silicon nanoparticles for use in high-capacity lithium-ion batteries.将具有导电性的 Ni(2,3,6,7,10,11-六氨基三苯) 金属-有机骨架与硅纳米颗粒耦合,用于高容量锂离子电池。
Nanoscale. 2020 Jan 23;12(3):1629-1642. doi: 10.1039/c9nr08038d.
3
Direct Electrodeposition of Electrically Conducting Ni(HITP) MOF Nanostructures for Micro-Supercapacitor Integration.用于微超级电容器集成的导电Ni(HITP)金属有机框架纳米结构的直接电沉积
Small. 2024 Sep;20(36):e2401509. doi: 10.1002/smll.202401509. Epub 2024 May 2.
4
Conductive MOF electrodes for stable supercapacitors with high areal capacitance.用于具有高面电容的稳定超级电容器的导电 MOF 电极。
Nat Mater. 2017 Feb;16(2):220-224. doi: 10.1038/nmat4766. Epub 2016 Oct 10.
5
Conductive Ni(HITP) MOFs thin films for flexible transparent supercapacitors with high rate capability.用于具有高倍率性能的柔性透明超级电容器的导电镍(HITP)金属有机框架薄膜
Sci Bull (Beijing). 2020 Nov 15;65(21):1803-1811. doi: 10.1016/j.scib.2020.06.027. Epub 2020 Jun 19.
6
Confined Synthesis of Oriented Two-Dimensional Ni(hexaiminotriphenylene) Films for Electrocatalytic Oxygen Evolution Reaction.用于电催化析氧反应的取向二维Ni(六亚氨基三亚苯)薄膜的受限合成
Langmuir. 2020 Jul 7;36(26):7528-7532. doi: 10.1021/acs.langmuir.0c01128. Epub 2020 Jun 21.
7
Cu₃(hexaiminotriphenylene)₂: an electrically conductive 2D metal-organic framework for chemiresistive sensing.六氨基三苯并菲衍生的铜二维金属有机框架:用于电阻型化学传感的导电材料。
Angew Chem Int Ed Engl. 2015 Mar 27;54(14):4349-52. doi: 10.1002/anie.201411854. Epub 2015 Feb 9.
8
Metal-organic Kagome lattices M3(2,3,6,7,10,11-hexaiminotriphenylene)2 (M = Ni and Cu): from semiconducting to metallic by metal substitution.金属有机 Kagome 晶格 M3(2,3,6,7,10,11 - 六氨基三亚苯基)2(M = 镍和铜):通过金属取代从半导体转变为金属
Phys Chem Chem Phys. 2015 Feb 28;17(8):5954-8. doi: 10.1039/c4cp05328a.
9
Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2.由Ni3(六亚氨基三亚苯)2催化的电化学氧还原反应
Nat Commun. 2016 Mar 8;7:10942. doi: 10.1038/ncomms10942.
10
High electrical conductivity in Ni₃(2,3,6,7,10,11-hexaiminotriphenylene)₂, a semiconducting metal-organic graphene analogue.Ni₃(2,3,6,7,10,11-六氨基三苯并菲)₂中的高导电性,一种半导体金属有机类似石墨烯。
J Am Chem Soc. 2014 Jun 25;136(25):8859-62. doi: 10.1021/ja502765n. Epub 2014 Apr 25.

引用本文的文献

1
From 0D to 2D: microwave-assisted synthesis of electrically conductive metal-organic frameworks with controlled morphologies.从0维到2维:微波辅助合成具有可控形貌的导电金属有机框架材料。
Chem Sci. 2025 Jan 16;16(7):3168-3172. doi: 10.1039/d4sc07025a. eCollection 2025 Feb 12.
2
Revealing Ion Adsorption and Charging Mechanisms in Layered Metal-Organic Framework Supercapacitors with Solid-State Nuclear Magnetic Resonance.利用固态核磁共振揭示层状金属有机框架超级电容器中的离子吸附和充电机制
J Am Chem Soc. 2024 Aug 21;146(33):23171-23181. doi: 10.1021/jacs.4c05330. Epub 2024 Aug 12.
3
Understanding Electrolyte Ion Size Effects on the Performance of Conducting Metal-Organic Framework Supercapacitors.
理解电解质离子大小对导电金属有机框架超级电容器性能的影响。
J Am Chem Soc. 2024 May 8;146(18):12473-12484. doi: 10.1021/jacs.4c00508. Epub 2024 Apr 26.
4
Current perspectives, challenges, and future directions in the electrochemical detection of microplastics.微塑料电化学检测的当前观点、挑战及未来方向
RSC Adv. 2024 Jan 10;14(3):2134-2158. doi: 10.1039/d3ra06755f. eCollection 2024 Jan 3.
5
Experimental manifestation of redox-conductivity in metal-organic frameworks and its implication for semiconductor/insulator switching.金属有机框架中氧化还原导电性的实验表现及其对半导体/绝缘体切换的影响。
Nat Commun. 2023 Jul 20;14(1):4388. doi: 10.1038/s41467-023-40110-6.
6
Oxidative control over the morphology of Cu(HHTP), a 2D conductive metal-organic framework.二维导电金属有机框架Cu(HHTP)形态的氧化控制
Chem Sci. 2022 Aug 16;13(35):10472-10478. doi: 10.1039/d2sc03648g. eCollection 2022 Sep 14.
7
Enhancing the energy storage performances of metal-organic frameworks by controlling microstructure.通过控制微观结构提高金属有机框架的储能性能。
Chem Sci. 2022 Jul 18;13(32):9210-9219. doi: 10.1039/d2sc03389e. eCollection 2022 Aug 17.
8
Thousand-fold increase in O electroreduction rates with conductive MOFs.使用导电金属有机框架使O电还原速率提高千倍。
ACS Cent Sci. 2022 Jul 27;8(7):975-982. doi: 10.1021/acscentsci.2c00509. Epub 2022 Jul 1.