Zhou Yujiao, Avila Jocasta, Berthet Nicolas, Legrand Solène, Santini Catherine C, Costa Gomes Margarida, Dufaud Véronique
University of Lyon, CPE Lyon, CNRS, UMR 5128, Catalysis, Polymerization, Processes and Materials (CP2M), 43 Bvd. du 11 Novembre 1918, F-69616 Villeurbanne, France.
Laboratoire de Chimie de l'ENS Lyon, CNRS and Université de Lyon, 46 allée dItalie, 69364 Lyon, France.
Chem Commun (Camb). 2021 Aug 10;57(64):7922-7925. doi: 10.1039/d1cc02642a.
Porous ionic liquids combining alkylphosphonium halides with ZIF-8 absorb large amounts of carbon dioxide that can be catalytically coupled with epoxides to form cyclic carbonates. High activity and selectivity under mild reaction conditions points towards a new promising, high-performing, sustainable family of sorbents for simultaneous carbon capture and transformation.
将烷基卤化鏻与ZIF-8相结合的多孔离子液体可吸收大量二氧化碳，这些二氧化碳可与环氧化物催化偶联形成环状碳酸酯。在温和反应条件下具有高活性和选择性，这表明一种用于同时进行碳捕获和转化的新型、有前景、高性能、可持续的吸附剂家族。
