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南极海洋(乔治王岛)的化学污染来源与组成,第 2 部分:华沙冰原积雪覆盖层中的有机和无机化学物质。

Sources and composition of chemical pollution in Maritime Antarctica (King George Island), part 2: Organic and inorganic chemicals in snow cover at the Warszawa Icefield.

机构信息

Kazimierz Wielki University, Institute of Geography, 8 Kościelecki Sq., 85-033 Bydgoszcz, Poland.

Gdansk University of Technology, Faculty of Chemistry, Analytical Chemistry Department, 11/12 Narutowicza St., Gdansk 80-233, Poland.

出版信息

Sci Total Environ. 2021 Nov 20;796:149054. doi: 10.1016/j.scitotenv.2021.149054. Epub 2021 Jul 15.

DOI:10.1016/j.scitotenv.2021.149054
PMID:34328894
Abstract

The study area is located on King George Island, where 90% of the area is permanently glaciated. This study provides a comprehensive analysis of the inorganic and organic chemistry of snow cover in the icefield and a comparison against previous results obtained in fresh water. Snow samples were collected in the summer of 2017 in the Warszawa Icefield area. Sampling points are located along two transects: between the Arctowski Polish Polar Station and the Carlini Base (N = 4), and from the forefield to the upper part of Ecology Glacier (N = 5). In the snow samples, (1) basic ions, (2) major trace metals and metalloids (and B), and (3) polycyclic aromatic hydrocarbons (PAHs) were detected and quantified. Additionally, the parameters of pH, specific electrolytic conductivity (SEC) and total organic carbon (TOC) were determined. The results show a low concentration of inorganic elements (<30 mg/L), TOC (<1 mg/L) and PAHs (0.11-1.4 ng/L) in collected snow samples. A slight increase in PAHs and heavy-metals concentration has been observed at the marginal parts of the icefield, which suggests the impact of scientific stations. Based on this result there is a need to conduct research on pollutant levels in ice cores on King George Island to assess the risk associated with rapid glacier thawing and pollution remobilisation.

摘要

研究区域位于乔治王岛,该地区 90%的面积被永久冰川覆盖。本研究全面分析了冰原上雪盖的无机和有机化学,并与之前在淡水环境中获得的结果进行了比较。雪样于 2017 年夏季在华沙冰原地区采集。采样点位于两条测线上:从阿图什波兰极地站到卡利尼基地(N = 4)之间,以及从前缘到生态冰川上部(N = 5)。在雪样中,检测和定量了 (1) 碱性离子、(2) 主要痕量金属和类金属(和 B)以及 (3) 多环芳烃 (PAHs)。此外,还测定了 pH 值、特定电导率 (SEC) 和总有机碳 (TOC) 等参数。结果表明,采集的雪样中无机元素(<30 mg/L)、TOC(<1 mg/L)和 PAHs(0.11-1.4 ng/L)浓度较低。在冰原边缘部分观察到 PAHs 和重金属浓度略有增加,这表明受到了科学站的影响。根据这一结果,有必要对乔治王岛上冰芯中的污染物水平进行研究,以评估与冰川迅速融化和污染再移动相关的风险。

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