Institute of Nano Science and Nano Technology, University of Kashan, Kashan, P. O. Box.87317-51167, Iran.
Faculty of Chemistry, Razi University, Kermanshah 6714414971, Iran; Department of Chemistry, College of Science, University of Raparin, Rania, Kurdistan Region, Iraq.
Ultrason Sonochem. 2021 Sep;77:105678. doi: 10.1016/j.ultsonch.2021.105678. Epub 2021 Jul 24.
The deficiency of drinking water sources has become a serious crisis for the future of the world that the photocatalytic process is one of the most favorable methods for removal of artificial dyes and poisonous organic impurities. In the present study, rapid ultrasonic treatment was performed to obtain LaSnO/Graphitic carbon nitrides (LSO/CN) nanocomposites with advanced photo-catalytic performance. Broccoli extract was utilized as a natural surfactant with active surface groups to control nucleation and growth of formed crystals with the creation of spatial barriers around the cations, and finally prevent nano-product agglomeration. Changing experimental parameters in synthesis reaction in turn offers a virtuous control over the nano-products size and shape. The shape and size distribution of particles was considered via diverse characterization techniques of microscopic and spectroscopic. The photocatalytic behaviors along with a kinetic study of the nanoparticles were examined by elimination and degradation of different artificial dyes under the UV waves. Effect of particle size, weight ratio of LSO:CN, type of dye, scavenger kind, dye and catalyst loading was designated on altering proficiency of nano-catalyst function. Also, the probable mechanism of removal dye by photocatalytic function was studied.
饮用水源的短缺已成为世界未来的严重危机,光催化过程是去除人工染料和有毒有机杂质的最有利方法之一。在本研究中,采用快速超声处理方法获得具有先进光催化性能的 LaSnO/Graphitic carbon nitrides(LSO/CN)纳米复合材料。采用西兰花提取物作为天然表面活性剂,具有活性表面基团,可控制形成晶体的成核和生长,在阳离子周围形成空间障碍,最终防止纳米产品团聚。通过改变合成反应中的实验参数,可以对纳米产品的尺寸和形状进行良性控制。通过微观和光谱学的各种特征技术对颗粒的形状和尺寸分布进行了考虑。通过在 UV 光下消除和降解不同的人工染料,对纳米粒子的光催化行为和动力学进行了研究。研究了颗粒尺寸、LSO:CN 的重量比、染料类型、清除剂种类、染料和催化剂负载量对纳米催化剂功能改变效率的影响。此外,还研究了光催化作用去除染料的可能机制。