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组成和制备条件对基于Tokem - 200阳离子交换树脂的球形颗粒状复合材料TiO - SiO/CaO结构与性能的影响

Influence of Composition and Preparation Conditions on the Structure and Properties of Composite Materials TiO-SiO/CaO with a Spherical Particle Shape Based on Tokem-200 Cationic Exchange Resins.

作者信息

Kozik Vladimir V, Borilo Lyudmila P, Lyutova Ekaterina S, Chen Yu-Wen

机构信息

National Research Tomsk State University, 36 Lenina Avenue, Tomsk 634050, Russia.

Department of Chemical Engineering, National Central University, Jhongli, Chung-Li 32001 Taiwan.

出版信息

ACS Omega. 2021 Aug 4;6(32):21104-21112. doi: 10.1021/acsomega.1c02918. eCollection 2021 Aug 17.

Abstract

Spherical biomaterials based on Tokem-200 cationic exchange resin were synthesized from solutions by the sol-gel method. The material framework is represented by TiO-SiO, and the inner part is filled with CaO (sample TiO-SiO/CaO). A stepwise heat treatment (drying at 60 °C) annealing at 150, 250, and 350 °C, each for 30 min, at 600 °C for 6 h, and 800 °C for 1 h is required to obtain a homogeneous material. In simulated body fluid solution, the sample exhibited bioactive properties, and gelatin could be used as a binding additive.

摘要

基于Tokem - 200阳离子交换树脂的球形生物材料通过溶胶 - 凝胶法从溶液中合成。材料骨架由TiO - SiO表示,内部填充CaO(样品TiO - SiO/CaO)。为了获得均匀的材料,需要进行逐步热处理(在60°C干燥),在150、250和350°C下各退火30分钟,在600°C下退火6小时,在800°C下退火1小时。在模拟体液溶液中,该样品表现出生物活性,明胶可用作结合添加剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cbce/8375089/d6c3613b895b/ao1c02918_0002.jpg

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