ICGM, Univ Montpellier, CNRS, ENSCM, Montpellier 34000, France.
Biomacromolecules. 2021 Sep 13;22(9):3625-3648. doi: 10.1021/acs.biomac.1c00837. Epub 2021 Aug 31.
Biobased materials, derived from biomass building blocks, are essential in the pursuit of sustainable materials. Eugenol, a natural phenol obtained from clove oil, but also from lignin depolymerization, possesses a chemical structure that allows its easy modification to obtain a broad and versatile platform of biobased monomers. In this Perspective, an overview of the variety of reactions that have been executed on the allylic double bond, phenol hydroxyl group, aromatic ring, and methoxy group is given, focusing our attention on those to obtain monomers suitable for different polymerization reactions. Furthermore, possible applications and perspectives on the eugenol-derived materials are provided.
生物基材料来源于生物质单体，是追求可持续材料的关键。丁香酚是一种天然酚，可从丁香油中提取，也可从木质素解聚中获得，其化学结构使其易于修饰，从而获得广泛而多样的生物基单体平台。在本观点中，概述了已在烯丙基双键、苯酚羟基、芳环和甲氧基上进行的各种反应，重点关注那些可获得适合不同聚合反应的单体的反应。此外，还提供了丁香酚衍生材料的可能应用和前景。
