Spessa Alberto, Castiglione Franca, Vitale Alessandra, Bongiovanni Roberta, Dalle Vacche Sara
Department of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy.
Departiment of Chemistry Materials and Chemical Engineering "Giulio Natta", Politecnico di Milano, Via Luigi Mancinelli 7, 20131 Milano, Italy.
Polymers (Basel). 2024 Dec 20;16(24):3570. doi: 10.3390/polym16243570.
Bio-derived monomers and biobased building blocks obtained from natural sources, e.g., fats and oils, are attracting increasing attention mainly due to sustainability concerns. Due to their features, renewable feedstocks are an excellent alternative to petroleum-based raw materials to shift towards greener chemistry, especially when coupled with energy-efficient processes like photopolymerization. In this review, we illustrate the recent research outcomes in the field of photocurable biobased monomers, showing the advantages of using biobased chemicals for the synthesis of photocurable monomers and the potential of naturally derived building blocks in photocuring reactions.
从天然来源(如油脂)获得的生物衍生单体和生物基结构单元,主要由于可持续性方面的考虑而受到越来越多的关注。由于其特性,可再生原料是石油基原料向绿色化学转变的极佳替代品,特别是当与光聚合等节能工艺相结合时。在本综述中,我们阐述了光固化生物基单体领域的最新研究成果,展示了使用生物基化学品合成光固化单体的优势以及天然衍生结构单元在光固化反应中的潜力。