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利用湖泊沉积物和蓝藻生产多孔轻质骨料(陶粒)。

Co-utilization of lake sediment and blue-green algae for porous lightweight aggregate (ceramsite) production.

机构信息

School of Chemistry and Materials Science, School of Environment, Jiangsu Provincial Key Laboratory of Material Cycling and Pollution Control, Nanjing Normal University, Nanjing, 210046, China.

School of Chemistry and Materials Science, School of Environment, Jiangsu Provincial Key Laboratory of Material Cycling and Pollution Control, Nanjing Normal University, Nanjing, 210046, China.

出版信息

Chemosphere. 2022 Jan;287(Pt 2):132145. doi: 10.1016/j.chemosphere.2021.132145. Epub 2021 Sep 3.

Abstract

Lake sediment and algal sludge with large output posed significant environmental risks. In this work, an idea of co-utilization of both solid wastes for the production of ceramsite (a sort of porous lightweight aggregates as building materials) was proposed and validated for the first time. The treatment process contained a dewatering step by a flocculation-pressure filtration method, and a sintered ceramsite preparation step. Effects of flocculant type and dosage on the dewatering performance were studied in the first step. An environmental-friendly amphoteric starch flocculant with a dosage of 12 mg/(g dried sample) was found to achieve the best dewatering performance. Effects of raw material mass ratio, sintering temperature and time in the second step were investigated. Under the optimal conditions (60 wt% of dewatered sediment; 20 wt% of dewatered algal sludge; 20 wt% of additives (fly ash: calcium oxide: kaolin = 2:1:2); sintering temperature: 1100 °C; time: 35 min), the obtained ceramsite met the Chinese National Standard as a qualified building material, with reliable environmental safety according to the leaching results for both heavy metals and microcystins. Both environmental and economic benefits of the proposed treatment were assessed. The process completely followed the rules of "reduction, harmlessness and resource utilization" for solid waste treatment and disposal; Meanwhile, the profit of the proposed ceramsite production could be more than 2.3 US dollar/m. The co-utilization method in this work acted as a good example for the comprehensive management of solid wastes in water-rich areas.

摘要

大量产出的湖泊沉积物和藻类污泥带来了重大的环境风险。在这项工作中,首次提出并验证了同时利用这两种固体废物生产陶粒(一种用作建筑材料的多孔轻质骨料)的想法。该处理工艺包括絮凝-压滤脱水步骤和烧结陶粒制备步骤。在第一步中,研究了絮凝剂类型和用量对脱水性能的影响。发现一种环保的两性淀粉絮凝剂,用量为 12 mg/(干样 g),具有最佳的脱水性能。在第二步中,考察了原料质量比、烧结温度和时间的影响。在最佳条件下(脱水沉积物 60wt%;脱水藻类污泥 20wt%;添加剂(粉煤灰:氧化钙:高岭土=2:1:2)20wt%;烧结温度:1100°C;时间:35min),所得陶粒符合中国国家标准,是一种合格的建筑材料,根据重金属和微囊藻毒素的浸出结果,具有可靠的环境安全性。评估了所提出的处理方法的环境和经济效益。该工艺完全遵循固体废物处理和处置的“减量化、无害化和资源化”原则;同时,所提出的陶粒生产利润可以超过 2.3 美元/m。这项工作中的联合利用方法为富水地区固体废物的综合管理提供了一个很好的范例。

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