Propelling the practical application of the intimate coupling of photocatalysis and biodegradation system: System amelioration, environmental influences and analytical strategies.

The intimate coupling of photocatalysis and biodegradation (ICPB) possesses an enhanced ability of recalcitrant contaminant removal and energy generation, owing to the compact communication between biotic components and photocatalysts during the system operation. The photocatalysts in the ICPB system could dispose of noxious contaminants to relieve the external pressure on microorganisms which could realize the mineralization of the photocatalytic degradation products. However, due to the complex components in the composite system, the mechanism of the ICPB system has not been completely understood. Moreover, the variable environmental conditions would play a significant role in the ICPB system performance. The further development of the ICPB scheme requires clarification on how to reach an accurate understanding of the system condition during the practical application. This review starts by offering detailed information on the system construction and recent progress in the system components' amelioration. We then describe the potential influences of relevant environmental factors on the system performance, and the analytical strategies applicable for comprehending the critical processes during the system operation are further summarized. Finally, we put forward the research gaps in the current system and envision the system's prospective application. This review provides a valuable reference for future researches that are devoted to assessing the environmental disturbance and exploring the reaction mechanisms during the practical application of the ICPB system.