Department of Earth and Environmental Sciences, The University of Manchester, Manchester, UK.
Leibniz Universität Hannover, Institut für Mineralogie, Hannover, Germany.
Nat Commun. 2021 Sep 17;12(1):5495. doi: 10.1038/s41467-021-25820-z.
Basaltic crystal cargoes often preserve records of mantle-derived chemical variability that have been erased from their carrier liquids by magma mixing. However, the consequences of mixing between similarly primitive but otherwise chemically variable magmas remain poorly understood despite ubiquitous evidence of chemical variability in primary melt compositions and mixing-induced disequilibrium within erupted crystal cargoes. Here we report observations from magma-magma reaction experiments performed on analogues of primitive Icelandic lavas derived from distinct mantle sources to determine how their crystal cargoes respond to mixing-induced chemical disequilibrium. Chemical variability in our experimental products is controlled dominantly by major element diffusion in the melt that alters phase equilibria and triggers plagioclase resorption within regions that were initially plagioclase saturated. Isothermal mixing between chemically variable basaltic magmas may therefore play important but previously underappreciated roles in creating and modifying crystal cargoes by unlocking plagioclase-rich mushes and driving resorption, (re-)crystallisation and solid-state diffusion.
玄武质晶体负载物通常保存有地幔源化学变化的记录,而这些变化在岩浆混合过程中已从其载体液体中被抹去。然而,尽管在原始熔体成分中存在普遍的化学变化证据,以及在喷发的晶体负载物中存在混合诱导的不平衡,但对于类似原始但在其他方面具有化学变化的岩浆之间的混合的后果仍了解甚少。在这里,我们报告了在源自不同地幔源的原始冰岛熔岩类似物上进行的岩浆-岩浆反应实验的观察结果,以确定它们的晶体负载物如何对混合诱导的化学不平衡做出响应。我们实验产物中的化学变化主要受熔体中主要元素扩散的控制,这改变了相平衡,并在最初为斜长石饱和的区域内引发斜长石吸收。因此,化学变化的玄武质岩浆之间的等温混合可能通过解锁富含斜长石的糊状物质并驱动吸收、(再)结晶和固态扩散,在创造和修改晶体负载物方面发挥重要但以前未被充分认识的作用。