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基于锗的光引发剂是否有可能取代成熟的酰基膦氧化物？

Do germanium-based photoinitiators have the potential to replace the well-established acylphosphine oxides?

机构信息

Institute of Inorganic Chemistry, Graz University of Technology, Stremayrgasse 9/IV, 8010 Graz, Austria.

出版信息

Dalton Trans. 2021 Sep 21;50(36):12392-12398. doi: 10.1039/d1dt02308j.

DOI:10.1039/d1dt02308j
PMID:34545890
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8453693/
Abstract

In the last few decades, there has been an increasing demand for photoinitiators with growing requirements. Nowadays, photoinitiators need to fulfill several requirements such as a low level of toxicity, biocompatibility, fast polymerization rates, high activities, good photobleaching and much more in order to remain competitive on the market. Accordingly, we compare acylphosphine oxides and acylgermanes, two common classes of photoinitiators, with respect to their various synthetic pathways, toxicity, availability and performance.

摘要

在过去几十年中，人们对光引发剂的需求不断增加，要求也越来越高。如今，光引发剂需要满足多种要求，如低毒性、生物相容性、快速聚合速率、高活性、良好的光漂白性等等，才能在市场上保持竞争力。因此，我们比较了两种常见的光引发剂——酰基膦氧化物和酰基锗，从它们的各种合成途径、毒性、可得性和性能方面进行了比较。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/dae46f8009b3/d1dt02308j-p2.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/dae46f8009b3/d1dt02308j-p2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/c60c4c1ad74e/d1dt02308j-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/a3d5732d1837/d1dt02308j-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/f57c5912b36a/d1dt02308j-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/32daed837c08/d1dt02308j-s4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/dc488dff986b/d1dt02308j-s5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/887610fb3ad4/d1dt02308j-s6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/4c5655201f82/d1dt02308j-s7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/997b35cc2a84/d1dt02308j-s8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/a4782dc23795/d1dt02308j-s9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/6c5b926126b5/d1dt02308j-s10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/b278d5655c4c/d1dt02308j-s11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/aa676c2459ff/d1dt02308j-s12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/101a82f5c1ae/d1dt02308j-s13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/b3cdb479b01d/d1dt02308j-s14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/12d6a2973ac7/d1dt02308j-s15.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/80e59fdde7f7/d1dt02308j-p1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d8c/8453693/dae46f8009b3/d1dt02308j-p2.jpg

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