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基于锗的光引发剂化学的最新进展。

Recent Advances in Germanium-Based Photoinitiator Chemistry.

机构信息

Institute of Inorganic Chemistry, Technische Universität Graz, Stremayrgasse 9/IV, 8010, Graz, Austria.

Institute of Physical and Theoretical Chemistry, Technische Universität Graz, Stremayrgasse 9/IV, 8010, Graz, Austria.

出版信息

Chemistry. 2018 Jun 12;24(33):8258-8267. doi: 10.1002/chem.201705567. Epub 2018 Feb 26.

DOI:10.1002/chem.201705567
PMID:29356151
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6032850/
Abstract

Acylgermanes provide an outstanding photoinduced reactivity at very useful absorption wavelengths. This encouraged multidisciplinary research groups to utilize them as highly effective and non-toxic photoinitiators particularly for medical applications. In this Minireview, we present the most recent breakthroughs to synthesize acylgermanes. We also outline mechanistic aspects of photoinduced reactions of several acylgermane derivatives based on fundamental spectroscopic insights. These studies may aid future developments for tailor-made photoinitiators.

摘要

酰基锗烷在非常有用的吸收波长下提供了出色的光致反应性。这鼓励了多学科研究小组将其用作高效且无毒的光引发剂，特别是在医学应用中。在这篇综述中，我们介绍了合成酰基锗烷的最新突破。我们还根据基本光谱见解概述了几种酰基锗烷衍生物的光诱导反应的机理方面。这些研究可能有助于未来为定制光引发剂的发展。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1dd5/6032850/d3ba865bc76c/CHEM-24-8258-g012.jpg
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