Orlandini Enzo, Micheletti Cristian
Department of Physics and Astronomy, University of Padova and Sezione INFN, Via Marzolo 8, Padova, Italy.
SISSA, International School for Advanced Studies, via Bonomea 265, Trieste, Italy.
J Phys Condens Matter. 2021 Oct 26;34(1). doi: 10.1088/1361-648X/ac28bf.
Linking, or multicomponent topological entanglement, is ubiquitous in soft matter systems, from mixtures of polymers and DNA filaments packedto interlocked line defects in liquid crystals and intertwined synthetic molecules. Yet, it is only relatively recently that theoretical and experimental advancements have made it possible to probe such entanglements and elucidate their impact on the physical properties of the systems. Here, we review the state-of-the-art of this rapidly expanding subject and organize it as follows. First, we present the main concepts and notions, from topological linking to physical linking and then consider the salient manifestations of molecular linking, from synthetic to biological ones. We next cover the main physical models addressing mutual entanglements in mixtures of polymers, both linear and circular. Finally, we consider liquid crystals, fluids and other non-filamentous systems where topological or physical entanglements are observed in defect or flux lines. We conclude with a perspective on open challenges.
连接,即多组分拓扑缠结,在软物质系统中无处不在,从聚合物与DNA细丝的混合物,到液晶中的互锁线缺陷以及相互缠绕的合成分子。然而,直到最近,理论和实验的进展才使得探测此类缠结并阐明它们对系统物理性质的影响成为可能。在这里,我们回顾这一快速发展主题的最新进展,并按如下方式进行组织。首先,我们介绍主要概念,从拓扑连接到物理连接,然后考虑分子连接的显著表现,从合成分子到生物分子。接下来,我们涵盖处理线性和环状聚合物混合物中相互缠结的主要物理模型。最后,我们考虑在缺陷或通量线中观察到拓扑或物理缠结的液晶、流体及其他非丝状系统。我们以对开放挑战的展望作为总结。