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由氧化石墨烯纳米片覆盖的高度柔性银纳米线网络,用于高性能柔性电子器件和抗菌应用。

Highly flexible Ag nanowire network covered by a graphene oxide nanosheet for high-performance flexible electronics and anti-bacterial applications.

作者信息

Sim Hyeong-Min, Kim Han-Ki

机构信息

School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon-si, Republic of Korea.

出版信息

Sci Technol Adv Mater. 2021 Sep 15;22(1):794-807. doi: 10.1080/14686996.2021.1963640. eCollection 2021.

DOI:10.1080/14686996.2021.1963640
PMID:34552391
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8451606/
Abstract

We investigated a flexible and transparent conductive electrode (FTCE) based on Ag nanowires (AgNWs) and a graphene oxide (GO) nanosheet and fabricated through a simple and cost-effective spray coating method. The AgNWs/GO hybrid FTCE was optimized by adjusting the nozzle-to-substrate distance, spray speed, compressor pressure, and volume of the GO solution. The optimal AgNWs/GO hybrid FTCE has a high transmittance of 88% at a wavelength of 550 nm and a low sheet resistance of 20 Ohm/square. We demonstrate the presence of the GO nanosheet on the AgNWs through Raman spectroscopy. Using scanning electron microscopy and atomic force microscopy, we confirmed that the nanosheet acted as a conducting bridge between AgNWs and improved the surface morphology and roughness of the electrode. Effective coverage by the GO sheet improved the conductivity of the AgNWs electrode Effective coverage of the GO sheet improved conductivity of the AgNWs electrode with minimum degradation of optical and mechanical properties. Flexible thin film heater (TFH) and electroluminescent (EL) devices fabricated on AgNWs/GO hybrid FTCEs showed better performance than devices on bare AgNWs electrodes due to lower sheet resistance and uniform conductivity. In addition, an AgNWs/GO electrode layer on a facial mask acts as a self-heating and antibacterial coating. A facial mask with an AgNWs/GO electrode showed a bacteriostatic reduction rate of 99.7 against and .

摘要

我们研究了一种基于银纳米线(AgNWs)和氧化石墨烯(GO)纳米片的柔性透明导电电极(FTCE),并通过一种简单且经济高效的喷涂方法制备而成。通过调整喷嘴与基板的距离、喷涂速度、压缩机压力和GO溶液的体积,对AgNWs/GO混合FTCE进行了优化。最佳的AgNWs/GO混合FTCE在550 nm波长处具有88%的高透过率和20 Ohm/方的低方块电阻。我们通过拉曼光谱证实了GO纳米片在AgNWs上的存在。使用扫描电子显微镜和原子力显微镜,我们确认纳米片充当了AgNWs之间的导电桥,并改善了电极的表面形态和粗糙度。GO片的有效覆盖提高了AgNWs电极的导电性,GO片的有效覆盖在光学和机械性能最小程度下降的情况下提高了AgNWs电极的导电性。在AgNWs/GO混合FTCE上制造的柔性薄膜加热器(TFH)和电致发光(EL)器件由于较低的方块电阻和均匀的导电性,表现出比在裸AgNWs电极上的器件更好的性能。此外,面罩上的AgNWs/GO电极层可作为自热和抗菌涂层。带有AgNWs/GO电极的面罩对[具体细菌1]和[具体细菌2]的抑菌率为99.7%。

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