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材料性能对采用球形腔混合器制备的聚丙烯基木塑复合材料发泡行为的影响

Effect of Material Properties on the Foaming Behaviors of PP-Based Wood Polymer Composites Prepared with the Application of Spherical Cavity Mixer.

作者信息

Wang Suwei, Xue Ping, Zhang Wenxin, Hao Gazi, Xiao Lei, Jiang Wei

机构信息

National Special Superfine Powder Engineering Research Center of China, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.

College of Mechanical and Electrical Engineering, Beijing University of Chemical Technology, Beijing 100029, China.

出版信息

Polymers (Basel). 2021 Sep 19;13(18):3179. doi: 10.3390/polym13183179.

Abstract

For the low weight and high strength, the microcellular extrusion foaming technology was applied in the preparation of polypropylene (PP)-based wood polymer composites, and the spherical cavity mixer was used to construct an experimental platform for the uniform dispersion of wood flour (WF). The effects of PP molecular configuration on the composite properties and cell morphology of samples were also investigated. The experimental results indicated that the application of a spherical cavity mixer with a cavity radius of 5 mm could effectively improve the mixing quality and avoid the agglomeration of WF. In addition, compared with the branched molecule, the linear molecule not only increased the melting temperature by about 10 °C, but also endowed composites with a higher complex viscosity at a shear rate lower than 100 s, which contributed to the cell morphology of more microporous samples.

摘要

针对低重量和高强度的需求,将微孔挤出发泡技术应用于聚丙烯(PP)基木塑复合材料的制备中,并使用球形腔混合器构建了一个用于木粉(WF)均匀分散的实验平台。还研究了PP分子构型对样品复合性能和泡孔形态的影响。实验结果表明,使用腔半径为5 mm的球形腔混合器可以有效提高混合质量并避免WF的团聚。此外,与支化分子相比,线性分子不仅使熔融温度提高了约10℃,而且在剪切速率低于100 s时赋予复合材料更高的复数黏度,这有助于形成更多微孔样品的泡孔形态。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8780/8472921/b022c2503c08/polymers-13-03179-g001.jpg

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