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纳米纤维纱线的静电纺丝机理及其多尺度包覆纱线

Electrospinning Mechanism of Nanofiber Yarn and Its Multiscale Wrapping Yarn.

作者信息

Yan Taohai, Shi Yajing, Zhuang Huimin, Lin Yu, Lu Dongdong, Cao Shengbin, Zhu Lvtao

机构信息

Fujian Key Laboratory of Novel Functional Textile Fibers and Materials, Minjiang University, Fuzhou 350108, China.

Key Lab for Sport Shoes Upper Materials of Fujian Province, Fujian Huafeng New Material Co., Ltd., Putian 351199, China.

出版信息

Polymers (Basel). 2021 Sep 20;13(18):3189. doi: 10.3390/polym13183189.

Abstract

To analyze the feasibility of electrospinning nanofiber yarn using a wrapping yarn forming device, electrospun nanofiber-wrapped yarns and multiscale yarns were prepared by self-made equipment. The relationship between the surface morphology and properties of yarn and its preparation process was studied. The process parameters were adjusted, and it was found that some nanofibers formed Z-twisted yarns, while others showed exposed cores. To analyze the forming mechanism of electrospun nanofiber-wrapped yarn, the concept of winding displacement difference in the twisted yarn core was introduced. The formation of nanofiber-wrapped structural yarns was discussed using three values of . The starting point of each twist was the same position when = 0 with a constant corner angle β. However, the oriented nanofiber broke or was pulled out from the gripping point when it was twisted, and it appeared disordered. The forming process of electrospun nanofiber-wrapped yarn displayed some unique phenomena, including the emission of directional nanofibers during collection, fiber non-continuity, and twist angle non-uniformity. The conclusions of this research have theoretical and practical value to guide the industrial preparation of nanofiber yarns and their wrapped yarns.

摘要

为分析采用包覆纱成型装置制备静电纺纳米纤维纱的可行性,利用自制设备制备了静电纺纳米纤维包覆纱和多尺度纱。研究了纱线的表面形态、性能与其制备工艺之间的关系。通过调整工艺参数,发现部分纳米纤维形成了Z捻纱,而部分则呈现出芯部外露的情况。为分析静电纺纳米纤维包覆纱的成型机理,引入了捻纱芯部卷绕位移差的概念。利用三个值探讨了纳米纤维包覆结构纱的形成过程。当 = 0且角β恒定时,每次加捻的起始点位于相同位置。然而,取向纳米纤维在加捻时会从握持点断裂或被拉出,从而出现无序状态。静电纺纳米纤维包覆纱的成型过程呈现出一些独特现象,包括收集过程中定向纳米纤维的发射、纤维的不连续性以及捻角的不均匀性。本研究的结论对于指导纳米纤维纱及其包覆纱的工业化制备具有理论和实际价值。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/013f/8471309/600b65f12b08/polymers-13-03189-g001.jpg

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