Kuzmina Anna, Parzefall Markus, Back Patrick, Taniguchi Takashi, Watanabe Kenji, Jain Achint, Novotny Lukas
Photonics Laboratory, ETH Zürich, 8093 Zürich, Switzerland.
International Center for Materials Nanoarchitectonics, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan.
Nano Lett. 2021 Oct 13;21(19):8332-8339. doi: 10.1021/acs.nanolett.1c02913. Epub 2021 Oct 4.
Single-layer graphene has many remarkable properties but does not lend itself as a material for light-emitting devices as a result of its lack of a band gap. This limitation can be overcome by a controlled stacking of graphene layers. Exploiting the unique Dirac cone band structure of graphene, we demonstrate twist-controlled resonant light emission from graphene/hexagonal boron nitride (h-BN)/graphene tunnel junctions. We observe light emission irrespective of the crystallographic alignment between the graphene electrodes. Nearly aligned devices exhibit pronounced resonant features in both optical and electrical characteristics that vanish rapidly for twist angles θ ≳3°. These experimental findings can be well-explained by a theoretical model in which the spectral photon emission peak is attributed to photon-assisted momentum conserving electron tunneling. The resonant peak in our aligned devices can be spectrally tuned within the near-infrared range by over 0.2 eV, making graphene/h-BN/graphene tunnel junctions potential candidates for on-chip optoelectronics.
单层石墨烯具有许多卓越的特性,但由于其缺乏带隙,因此并不适合作为发光器件的材料。通过对石墨烯层进行可控堆叠,可以克服这一限制。利用石墨烯独特的狄拉克锥能带结构,我们展示了石墨烯/六方氮化硼(h-BN)/石墨烯隧道结中扭转控制的共振发光。我们观察到,无论石墨烯电极之间的晶体取向如何,都会有发光现象。几乎对齐的器件在光学和电学特性上都表现出明显的共振特征,当扭转角θ≳3°时,这些特征会迅速消失。这些实验结果可以通过一个理论模型得到很好的解释,在该模型中,光谱光子发射峰归因于光子辅助的动量守恒电子隧穿。我们对齐器件中的共振峰可以在近红外范围内进行超过0.2 eV的光谱调谐,这使得石墨烯/h-BN/石墨烯隧道结成为片上光电子学的潜在候选材料。