基于普鲁士蓝的纳米酶“人工过氧化物酶”的流动电化学合成。
Flow-electrochemical synthesis of Prussian Blue based nanozyme 'artificial peroxidase'.
机构信息
Chemistry faculty of M.V. Lomonosov Moscow State University, Leninskie Gory 1, 119991 Moscow, Russia.
出版信息
Dalton Trans. 2021 Sep 7;50(33):11385-11389. doi: 10.1039/d1dt02107a. Epub 2021 Aug 17.
PMID:34612266
Abstract
We report on fully electrochemical flow-through synthesis of Prussian Blue based nanozymes defeating peroxidase in terms of more than 200 times higher catalytic rate constant (k = 6 × 10 s). Being reagentless, reproducible, simple and scalable, the proposed approach blazes new trails for the electrosynthesis of functional conductive and electroactive nanomaterials.
摘要
我们报告了基于普鲁士蓝的纳米酶的全电化学流动合成，其催化速率常数（k = 6 × 10 s）比过氧化物酶高 200 多倍。该方法无需试剂、可重复、简单且可扩展，为功能导电和电化学活性纳米材料的电合成开辟了新途径。
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