Center for Advanced Optoelectronic Functional Materials Research, and Key Lab of UV-Emitting Materials and Technology of Ministry of Education, Northeast Normal University, 5268 Renmin Street, Changchun 130024, China.
ACS Appl Mater Interfaces. 2021 Oct 20;13(41):49085-49095. doi: 10.1021/acsami.1c14523. Epub 2021 Oct 6.
All-paper sensors that are capable of free cutting and folding maximize the merits of papers, which fully utilize the unique potential of papers in cost effectiveness, flexibility, disposability, biodegradability, and a flexible design. However, most of the paper sensors have applied metals as the electrodes and polyimide/polydimethylsiloxane as the encapsulation/sensitive layers, limiting the advantages of the paper sensor. In this work, an all-paper, shape-designable, and reconfigurable capacitive pressure/proximity sensor is fabricated with multilayered tissue paper as the dielectric and polypyrrole printer paper as the electrode/encapsulation. Without the restriction of heterogeneous materials, the all-paper components enable the sensors' flexible shape design for freely cuttable and foldable 2D and 3D sensors including a 2D braille keyboard and even allow reconfiguration from a 3D box sensor to a 3D candy sensor. The all-paper sensor presents superior pressure-sensing performance (0.96 kPa at <1.76 kPa and 0.09 kPa at 1.76-22 kPa) and proximity-sensing ability. The sensing mechanism of the sensor is directly revealed from tissue paper changes using in situ 3D microscopy and dielectric measurement experiments. These results provide inspiration for realizing shape-designable and reconfigurable 3D sensors and fully demonstrate the application potential in omnidirectional perception, stretchable sensors, and green electronics.
能够自由切割和折叠的全纸质传感器最大限度地发挥了纸张的优点,充分利用了纸张在成本效益、灵活性、可处置性、生物降解性和灵活设计方面的独特潜力。然而,大多数纸质传感器都将金属用作电极,将聚酰亚胺/聚二甲基硅氧烷用作封装/敏感层,限制了纸质传感器的优势。在这项工作中,使用多层纸巾作为介电层,用聚吡咯打印纸作为电极/封装,制作了一种全纸质、可设计形状和可重构的电容式压力/接近传感器。由于没有异种材料的限制,全纸质组件使传感器能够灵活设计形状,可自由切割和折叠的 2D 和 3D 传感器,包括 2D 盲文键盘,甚至允许从 3D 盒式传感器重新配置为 3D 糖果传感器。全纸质传感器具有优异的压力传感性能(在<1.76kPa 时为 0.96kPa,在 1.76-22kPa 时为 0.09kPa)和接近传感能力。使用原位 3D 显微镜和介电测量实验直接揭示了传感器的传感机制。这些结果为实现可设计形状和可重构的 3D 传感器提供了启示,并充分展示了在全方位感知、可拉伸传感器和绿色电子领域的应用潜力。