铱催化的羧酸对仲烯丙醇的区域和对映选择性烯丙酯酯化反应。
Iridium-catalyzed regio- and enantioselective allylic esterification of secondary allylic alcohols with carboxylic acids.
机构信息
Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China.
出版信息
Chem Commun (Camb). 2021 Oct 21;57(84):11080-11083. doi: 10.1039/d1cc04861a.
PMID:34617093
Abstract
We report herein an iridium-catalyzed asymmetric allylic esterification of racemic secondary allylic alcohols using free carboxylic acids as nucleophiles under mild conditions with broad functional group tolerance, exhibiting excellent regio- and enantioselectivity .
摘要
我们在此报告了一种铱催化的外消旋仲烯丙醇的不对称烯丙基酯化反应，在温和条件下使用游离羧酸作为亲核试剂，具有广泛的官能团耐受性，表现出优异的区域和对映选择性。
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