Laboratorium für Organische Chemie, ETH Hönggerberg, Zürich, Switzerland.
Angew Chem Int Ed Engl. 2012 Apr 2;51(14):3470-3. doi: 10.1002/anie.201108287. Epub 2012 Feb 17.
The direct route: iridium-catalyzed direct conversion of branched allylic alcohols into enantioenriched branched primary allylic amines is highly regio- and enantioselective.
铱催化的支链烯丙醇直接转化为对映富集的支链伯烯丙基胺具有高度的区域和对映选择性。